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Chemical resistance evaluation of polystyrene / polypropylene blends : effect of blend compositions and SEBS comtent

机译:聚苯乙烯/聚丙烯共混物的耐化学性评估:共混物组成和SEBS含量的影响

摘要

The present study investigates the effect of styrene-b-(ethylene-co-butylenes)-udb-styrene (SEBS) and blend ratio on the chemical resistance of PS/PP blends. Usinguda Brabender PL2000 twin-screw extruder, blends of PS rich PS/PP (composition ranging ofud90–60 wt % PS) containing different amount of SEBS were prepared and injectionudmoulded to be evaluated for chemical resistance. The results showed that theudchemical resistance of PS to acetone and tetrahydrofuran (THF) increased with increasingudPP content. The chemical resistance of PS/PP blends increased with increasingudSEBS content at relatively lower PP content but decreased with increasing SEBS contentudat higher PP content. Dynamic mechanical analysis showed that 60/40/25 PS/PP/udSEBS blends had better miscibility than 60/40/5 PS/PP/SEBS blends. However better miscibilityuddid not result in enhanced chemical resistance since SEBS itself was effected byudthe chemicals
机译:本研究研究苯乙烯-b-(乙烯-共-丁烯)- udb-苯乙烯(SEBS)和共混比对PS / PP共混物耐化学性的影响。使用Bradender PL2000双螺杆挤出机,制备了PS含量丰富的PS / PP(组成范围为 ud90–60 wt%PS)的掺合物,其中包含不同量的SEBS,并注塑成型,以评估其耐化学性。结果表明,随着 udPP含量的增加,PS对丙酮和四氢呋喃(THF)的耐化学腐蚀能力增强。在相对较低的PP含量下,PS / PP共混物的耐化学性随udSEBS含量的增加而增加,但随SEBS含量的增加 PP含量的增加而降低。动态力学分析表明,与60/40/5 PS / PP / SEBS共混物相比,60/40/25 PS / PP / udSEBS共混物具有更好的混溶性。但是,由于SEBS本身受化学物质的影响,因此更好的混溶性/未导致耐化学性的提高

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