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Influence of alcohol addition on the specific surface area of calcium hydroxide powder prepared from quicklime : -In case of the alcohol-water successive treatment-

机译:酒精的添加对生石灰制备的氢氧化钙粉末比表​​面积的影响:-在酒精-水连续处理的情况下-

摘要

The dioxin from the garbage incineration is one of the serious environmental problems in recentyears. As one of the dioxin preventive methods, there is a method using calcium hydroxideCa(OH), reacting the chlorine in combustion exhaust gas from garbage incineration. In thismethod, the surface area of calcium hydroxide can be considered to play an important role.However, the formation mechanism of surface area in the calcium hydroxide powder generated byreaction from quicklime has not been sufficiently elucidated up to now. In this paper, the increaseof surface area in the present method of direct mixing quicklime with alcohol is experimentally discussed.As the result, the followings were concluded.CD The method using alcohol-water successive treatment proposed in this paper attains largerspecific surface area of calcium hydroxide powder than that obtained from the conventionalmethod reported in the previous paper 7) of reacting quicklime with aqueous solution of alcohol.@ The alcohols with longer alkyl chain can be pointed out to be effective to increase specificsurface area of calcium hydroxide powder.
机译:垃圾焚烧产生的二恶英是近年来严重的环境问题之一。作为防止二恶英的方法之一,有一种使用氢氧化钙Ca(OH)使垃圾焚烧的燃烧废气中的氯反应的方法。在该方法中,可以认为氢氧化钙的表面积起着重要的作用。然而,到目前为止,还没有充分阐明由生石灰的反应产生的氢氧化钙粉末中表面积的形成机理。本文通过实验探讨了将生石灰与酒精直接混合的方法中表面积的增加。结果,得出以下结论。CD本文提出的采用酒精-水连续处理的方法可获得较大的钙比表面积氢氧化钙粉末比从先前论文7)中报道的常规方法获得的氢氧化钙粉末使生石灰与醇的水溶液反应。@具有更长烷基链的醇可以被认为对增加氢氧化钙粉末的比表面积是有效的。

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