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>An inverse technique to determine volatile organic compounds diffusion and partition coefficients in dry building material
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An inverse technique to determine volatile organic compounds diffusion and partition coefficients in dry building material
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机译:确定挥发性有机化合物在干建筑材料中扩散和分配系数的逆技术
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摘要
A mass transfer theory based model describing volatile organic compounds (VOCs) diffusion in dry building material was presented. Effects of some key parameters on the model output were theoretically studied. An inverse method was developed to estimate the diffusion coefficient (D) and partition coefficient (K) of VOC/material combination by utilizing dynamic chamber emission data. The present inverse parameter estimation problem was solved with Levenberg-Marquardt method of minimization of the ordinary least-squares norm. Sensitivity analysis showed the feasibility of simultaneous estimation of D and K. The present inverse method was first validated by a theoretical case. Measurements with different error levels were used to show their effects on the accuracy of the estimates. Results indicate that the present inverse method can be used to accurately estimate both D and K with the additional information of measured VOC concentration in chamber. Then experimental data of styrene/carpet combination obtained from standard field and laboratory emission cell emission test were used to determine D and K using the validated inverse method. Reliable results were obtained.
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