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Photocatalyst TiO2 supported on glass fiber for indoor air purification : effect of NO on the photodegradation of CO and NO2

机译:负载在玻璃纤维上的TiO2光催化剂用于室内空气净化:NO对CO和NO2光降解的影响

摘要

A synthetic photocatalyst TiO2 prepared using the sol-gel method showed a higher activity than commercial photocatalyst TiO2 (P25), for the photodegradation of NO and benzene, toluene, ethylbenzene, o-xylene (BTEX) at typical indoor air parts-per-billion (ppb) levels. The Brunauer-Emmett-Teller (BET) surface area was found to be the vital parameter for the increased activity of the photocatalyst. The photocatalyst was immobilized on a glass fiber filter and evaluated under different humidity levels and residence time. The conversion of the synthetic photocatalyst and P25 were adversely affected by the increase of humidity, and decreased with decreasing residence time. The synthetic photocatalyst, however, was less affected by the levels of humidity. To evaluate the feasibility of photocatalytic technology for indoor air purification, other common indoor air pollutants such as CO and NO2 at ppb levels were co-injected with NO. Results showed that the conversion of CO was not promoted by the photodegradation of NO. No competitive effect was Observed between CO and NO. The presence of NO promoted the conversion of NO2 while the conversion of NO is decreased due the competition of adsorption site on catalyst between NO and NO2.
机译:使用溶胶-凝胶法制备的合成光催化剂TiO2在典型的十亿分之几的室内空气中对NO和苯,甲苯,乙苯,邻二甲苯(BTEX)的光降解表现出比市售光催化剂TiO2(P25)高的活性。 (ppb)级别。发现Brunauer-Emmett-Teller(BET)表面积是增加光催化剂活性的重要参数。将光催化剂固定在玻璃纤维过滤器上,并在不同的湿度水平和停留时间下进行评估。合成光催化剂和P25的转化率受到湿度增加的不利影响,并且随着停留时间的减少而降低。然而,合成光催化剂受湿度水平的影响较小。为了评估光催化技术用于室内空气净化的可行性,将其他常见的室内空气污染物(例如ppb级的CO和NO2)与NO共同注入。结果表明,NO的光降解并没有促进CO的转化。在CO和NO之间未观察到竞争作用。 NO的存在促进了NO 2的转化,而NO的转化由于催化剂上的吸附位在NO和NO 2之间的竞争而降低。

著录项

  • 作者

    Ao CH; Lee SC; Yu JC;

  • 作者单位
  • 年度 2003
  • 总页数
  • 原文格式 PDF
  • 正文语种 eng
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