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Corrosion mechanisms and behavior of a P-130x Gr/6063 A1 composite in aqueous environments

机译:P-130x Gr / 6063 A1复合材料在水性环境中的腐蚀机理和行为

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摘要

The corrosion mechanisms and behavior of a P-130x graphite fiber reinforced 6063 aluminum composite laminate were studied. Electrochemical and total immersion tests were performed on the composite in 3.5% sodium chloride and 5.0% sodium sulfate solutions. The effects of pH, the presence of sulfite ions, various heat treatments, and electrolyte aeration were investigated. Some tests were also performed on control monolithic 6063 aluminum specimens. Immersion tests showed that when graphite fibers are exposed simultaneously with the matrix, then galvanic coupling is the principal corrosion mechanism in this composite. However, if the composite cross sectional edges are sealed from contact with the environment, then pitting attack of the surface foils becomes the principal mode of attack, especially in harsh environments (chloride and sulfite ions present in addition to low pH). This form of attack can eventually lead to galvanic corrosion. Low pH and the addition of sulfite ion significantly increase the susceptibility to localized corrosion and the rates of both general and galvanic corrosion. Progressive aging of the composite matrix decreases general corrosion rates in deaerated solutions. Electrolyte aeration results in a significant reduction in the composite's resistance to all forms of corrosion
机译:研究了P-130x石墨纤维增强6063铝复合层压板的腐蚀机理和行为。在3.5%的氯化钠和5.0%的硫酸钠溶液中对复合材料进行了电化学和总浸入测试。研究了pH值,亚硫酸根离子的存在,各种热处理和电解液通气的影响。还对对照整体式6063铝样品进行了一些测试。浸入测试表明,当石墨纤维与基质同时暴露时,电流耦合是该复合材料的主要腐蚀机理。但是,如果将复合横截面边缘密封起来使其不与环境接触,则表面箔的点蚀会成为主要的腐蚀方式,尤其是在恶劣的环境中(除了低pH值外还会存在氯离子和亚硫酸根离子)。这种侵蚀形式最终会导致电腐蚀。低pH值和亚硫酸根离子的添加​​显着增加了对局部腐蚀的敏感性以及一般腐蚀和电腐蚀的速率。复合基质的逐步老化降低了脱气溶液中的一般腐蚀速率。电解质曝气导致复合材料对所有形式腐蚀的抵抗力显着降低

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    Elkin Leslie R.;

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  • 年度 1990
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  • 原文格式 PDF
  • 正文语种 en_US
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