The measurement of the rates of hydroxyl radical reactions and the prediction of rate constants in alcohol combustion

摘要

Experimental studies on the reaction of OH with methanol andudethanol and theoretical studies on four of the reactions of theudprimary products of the reaction with methanol have been performed.udThe rates of the reaction of OH (X2 t) with the alcoholsudmethanol, ethanol and (D3) methanol have been determined in theudtemperature ranges 250-800K , 250-460K, and at 293K respectivelyudusing the technique of flash photolysis-resonance absorption.