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Soil-release behaviour of polyester fabrics after chemical modification with polyethylene glycol

机译:聚乙二醇改性后的涤纶织物去污性能

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摘要

The ease of cleaning the fibers depends, among other characteristics, on their hydrophilicity. Hydrophilic fibers are easy-wash materials but hydrophobic fibers are difficult to clean due to their higher water-repellent surfaces. This type of surfaces, like polyester (PET), produce an accumulation of electrostatic charges that adsorbs and retain dirt. Thus, the polyester soil-release properties can be increased by finishing processes that improve fiber hydrophilicity [1, 2]. In present study, PET fabric modification was described by using polyethylene glycol (PEG) and dimetilol dihidroxy ethylene urea chemically modified resin. Briefly, the modification process was carried out in two steps, one to hydrolyse the polyester and create hydroxyl and carboxylic acid groups on surface and the other to crosslink the PEG chains. The resulting materials were characterized by contact angle, DSC and FTIR- ATR methods. Additionally, the soil release behavior and mechanical properties of modified PET were evaluated. For the best process conditions, the resulted PET presented 0º contact angle, stain release grade of 5 and acceptable mechanical performance.
机译:除其他特征外,清洁纤维的难易程度还取决于其亲水性。亲水纤维是易于洗涤的材料,但是疏水纤维由于其较高的疏水表面而难以清洗。这种类型的表面(例如聚酯(PET))会产生积聚的静电电荷,从而吸收并保留污垢。因此,可通过可改善纤维亲水性的整理工艺来提高聚酯的去污性能[1、2]。在本研究中,通过使用聚乙二醇(PEG)和二甲酚二羟乙氧基乙烯脲化学改性树脂描述了PET织物改性。简而言之,改性过程分两个步骤进行,一个步骤是水解聚酯并在表面上产生羟基和羧酸基团,另一个步骤是将PEG链交联。通过接触角,DSC和FTIR-ATR方法表征所得材料。另外,评估了改性PET的去污行为和机械性能。在最佳工艺条件下,所得PET的接触角为0º,脱色等级为5,并且具有可接受的机械性能。

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