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Using a new developed die and different types of thermosetting resins to produce U200 profiles by pultrusion

机译:使用新开发的模具和不同类型的热固性树脂通过拉挤成型生产U200型材

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摘要

In this work, a new steel heated pultrusion die was designed, developed and manufactured to produce U200 glass fibre reinforced thermosetting matrix (GRP) profiles. The finite element analysis (FEA) was used to predict and optimise the developed die heating by using cylindrical electrical powered cartridges. To assess the new die performance it was mounted in the 120 kN pultrusion line of the Portuguese company Vidropol SA and used to produce continuously U200 profiles able to meet all requirements specified for the E23 grade accordingly to the European Standard EN 13706: 2002.After setting up the type, orientation and sequence of layers in the U 200 laminate, different types of thermosetting resins were used in its production. Orthophthalic, isophthalic and bisphenolic unsaturated polyester as well as vinylester resins were used to produce glass fibre reinforced U 200 composite profiles. All applied resins were submitted to SPI gel tests in order to select the more appropriated catalyst system and optimise the processing variables to be used in each case, namely, pultrusion pull-speed and die temperature. The best pultrusion operational conditions were selected by varying and monitoring the pull-speed and die temperature and, at the same time, measuring the temperature on the manufactured U 200 profile during processing.Finally, the produced U200 profiles were submitted to visual inspection, calcination and mechanical tests, namely, flexural, tensional and interlaminar shear strength (ILSS) tests, to assess their accomplishment with the EN 13706 requirements.
机译:在这项工作中,设计,开发和制造了一种新型的钢制加热拉挤模具,以生产U200玻璃纤维增​​强的热固性基体(GRP)型材。有限元分析(FEA)用于通过使用圆柱形电动墨盒来预测和优化已开发的模具加热。为了评估新模具的性能,将其安装在葡萄牙Vidropol SA的120 kN拉挤生产线中,并用于连续生产U200型材,这些型材能够满足欧洲标准EN 13706:2002规定的E23级所有要求。根据U 200层压板的层的类型,方向和顺序,在其生产中使用了不同类型的热固性树脂。使用邻苯二甲酸,间苯二甲酸和双酚不饱和聚酯以及乙烯基酯树脂生产玻璃纤维增​​强的U 200复合型材。所有应用的树脂均经过SPI凝胶测试,以选择更合适的催化剂体系并优化每种情况下使用的工艺变量,即拉挤拉伸速度和模头温度。通过改变和监控拉速和模具温度来选择最佳拉挤操作条件,同时在加工过程中测量制造的U 200型材的温度,最后将生产的U200型材进行目视检查,煅烧机械测试,即弯曲,拉伸和层间剪切强度(ILSS)测试,以评估其是否符合EN 13706要求。

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