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Hydrogen sulfide removal from biogas using a salak fruit seeds packed bed reactor with sulfur oxidizing bacteria as biofilm

机译:使用带有硫氧化细菌的萨拉克果籽填充床反应器从沼气中去除硫化氢

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摘要

A packed bed reactor was evaluated for hydrogen sulfide (H2S) removal by sulfur-oxidizing bacteria attached as a biofilm on salak fruit seeds (SFS). The bacteria were isolated from the sludge of the wastewater of a biogas plant. The promising isolate from the previous work was used in a biofilter, and its capacity to remove H2S was evaluated at effects of time of operation, effects of biogas flow rate, effects of axial distance, and packing material. Obtained results showed that isolate attached to SFS in an 80 cm height and 8 cm inside diameter biofilter column could decrease H2S in biogas from 142.48 ppm to 4.06 ppm (97.15% removal efficiency) for a biogas flow rate of 8550 g m3 h1 corresponding to a residence time of 4 h.Simple kinetic models of sulfide removal and bacterial growth was proposed to describe the operation of the biofilter. The radial H2S concentration gradient in the flowing gas is to be neglected so is the H2S concentration in the biofilm at certain axial distance. Meanwhile, the rate of H2S degradation was approximated by Monod type equation.The obtained simultaneous ordinary differential equations solved by Runge-Kutta method. Comparing the calculated results and the experimental data, it can be concluded that model proposed can sufficiently describe the performance of the H2S removal. The suitable values of the parameters are as follows: max = 0.0000007 (s1), KS = 0.0000039 (g cm3), kG = 0.0086 (cm s1), HS = 0.9 ((g cm3)/(g cm3)), and Yx/s = 10.
机译:对填充床反应器进行了评估,方法是通过以生物膜形式附着在Salak果实种子(SFS)上的硫氧化细菌去除硫化氢(H2S)。从沼气厂废水的污泥中分离出细菌。来自先前工作的有希望的分离物被用于生物滤池,并根据操作时间,沼气流速,轴向距离和填料的影响评估了其去除H2S的能力。获得的结果表明,在8550 g·m3·h1的沼气流量下,在80厘米高,内径为8厘米的生物滤池中连接到SFS的分离物可以将沼气中的H2S从142.48 ppm降至4.06 ppm(去除效率为97.15%)。停留时间为4小时。提出了简单的硫化物去除和细菌生长动力学模型来描述生物滤池的操作。可以忽略流动气体中的径向H2S浓度梯度,也可以忽略一定轴向距离的生物膜中的H2S浓度。同时,利用Monod型方程式估算了H2S的降解速率,并通过Runge-Kutta方法求解了所得的常微分方程组。比较计算结果和实验数据,可以得出结论,所提出的模型可以充分描述H2S去除的性能。参数的合适值如下:max = 0.0000007(s1),KS = 0.0000039(g cm3),kG = 0.0086(cm s1),HS = 0.9((g cm3)/(g cm3))和Yx / s = 10。

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