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Synthesis of new benzimidazole derivatives and their corrosion inhibition performance on mild steel in 0.5 M hydrochloric acid.

机译:新型苯并咪唑衍生物的合成及其在0.5 M盐酸中对低碳钢的缓蚀性能。

摘要

The influence of three newly synthesized benzimidazole derivatives on the corrosion inhibition of mild steeludin 0.5 M HCl solution is studied using mass loss and electrochemical techniques. The corrosion rateudwas found to be depends on concentration and temperature of the medium. Adsorption of all the three inhibitors obeys Langmuir isotherm model. Polarization curves indicated that the studied inhibitors are of mixed type. Electrochemical impedance spectroscopy explains the mechanism of inhibitor’s action. Various activation and adsorption thermodynamic parameters were calculated and discussed. The results obtained from weight loss and electrochemical studies are in good agreement with each other. Theudvariation in inhibitive efficiency mainly depends on theudtype and nature of the substituents present in theudinhibitor molecule
机译:利用质量损失和电化学技术研究了三种新合成的苯并咪唑衍生物对低碳钢 udin 0.5 M HCl溶液的缓蚀性能的影响。发现腐蚀速率取决于介质的浓度和温度。三种抑制剂的吸附均符合Langmuir等温线模型。极化曲线表明所研究的抑制剂是混合型的。电化学阻抗谱解释了抑制剂作用的机理。计算和讨论了各种活化和吸附热力学参数。从重量减轻和电化学研究获得的结果彼此吻合良好。抑制效率的变化主要取决于抑制剂分子中取代基的类型和性质

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