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The influence of Ru additions on the corrosion behaviour of WC-Co cemented carbide in corrosive media

机译:钌的添加对WC-Co硬质合金在腐蚀性介质中腐蚀行为的影响

摘要

The aim of the study is to investigate the influence of Ru additions on the corrosionudbehaviour of WC-Co cemented carbides when exposed in corrosive media. The studyudinvolved the characterisation of the microstructures, morphologies and phases presentudby using the optical microscopy, SEM, XRD and Raman spectroscopy before and afterudcorrosion. The corrosion behaviour was investigated using the electrochemicaludpolarization tests in 1M hydrochloric acid, 1M sodium chloride and synthetic mineudwater solutions. Three types of corrosion tests were done on the samples byudelectrochemical techniques: potential versus time test, potentiodynamic polarisationudscans and chronoamperometry.udRuthenium affects c in 1M H2SO4 and synthetic mine water, but not really in NaCludsolution. It was also observed that the passivity range and corrosion resistance decreasesudin order of synthetic mine water> sodium chloride> sulphuric acid. It also appears thatudRu is more effective in improving corrosion resistance in all the solutions than a smalludvanadium carbide addition. Therefore, ruthenium additions of up to 3 wt% Ru of theudWC-10%Co alloy increased the corrosion resistance of the WC-Co alloys. This isudattributed to the stabilization of the cobalt fcc phase due to ruthenium additions whileudhcp phase is obtained when there is no ruthenium additions.
机译:本研究的目的是研究暴露于腐蚀介质中的Ru添加量对WC-Co硬质合金的腐蚀行为的影响。该研究涉及了在腐蚀前和腐蚀后使用光学显微镜,SEM,XRD和拉曼光谱对微观结构,形貌和相的表征。在1M盐酸,1M氯化钠和合成矿井水溶液中使用电化学超极化试验研究了腐蚀行为。通过 ud电化学技术对样品进行了三种类型的腐蚀测试:电势对时间测试,电位动力学极化 udscan和计时电流法。 ud钌影响1M H2SO4和合成矿井水中的c,但实际上不影响NaCl udsolution。还观察到,钝化范围和耐腐蚀性按合成矿井水>氯化钠>硫酸的顺序降低。与所有少量碳化钨相比,在所有溶液中, udRu似乎在改善耐腐蚀性方面更有效。因此,添加最多3 wt%Ru udWC-10%Co合金的钌可提高WC-Co合金的耐腐蚀性。这归因于由于添加钌而使钴fcc相稳定,而当不添加钌时获得了udhcp相。

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