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Utilization of Carbonated BOF Slag as Partial Replacement of Aggregate in Cement Mortars

机译:利用碳酸转炉渣替代水泥砂浆中的骨料

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摘要

After direct mineral carbonation, a material rich in carbonates and with reduced quantities of free oxides is obtained. The aim of this work was to show that such materials can be used in the construction domain. Basic Oxygen Furnace (BOF) slag from the steelmaking process has been traditionally seen as unfit for bounded applications due to its propensity to swelling, resulting from hydration of its high free lime content. Here, BOF slag was crushed to suitable particle sizes, carbonated in an aqueous solution of carbonic acid, and utilized to replace 50% of natural sand aggregate in cement mortars. The mechanical and chemical properties of these mortars were compared to mortars containing non-carbonated slags, and a standard cement mortar as a reference. Tests were conducted to determine mortar flow and soundness, and cured mortar compressive strength and leaching tendencies. The results showed a satisfactory performance for all considered aspects (comparable with the reference) of the mortar sample containing 37.5 wt% (1.5 in 4 parts solids) carbonated BOF slag of u3c0.5 mm particle size.
机译:在直接矿物碳酸化之后,获得了一种富含碳酸盐且具有减少量的游离氧化物的材料。这项工作的目的是证明此类材料可以在建筑领域中使用。传统上,炼钢过程中产生的碱性氧气炉渣(BOF)由于其高游离石灰含量的水合而具有溶胀倾向,因此不适合有界应用。在这里,将BOF炉渣粉碎至合适的粒度,在碳酸水溶液中进行碳酸盐化,并用于替代水泥砂浆中的50%天然砂骨料。将这些砂浆的机械和化学性能与含有非碳酸矿渣的砂浆进行了比较,并以标准水泥砂浆为参考。进行测试以确定砂浆的流动性和稳固性,以及固化的砂浆抗压强度和浸出倾向。结果表明,砂浆样品的所有考虑方面(与基准相比)均具有令人满意的性能,该砂浆样品含37.5 wt%(每4份固体中的1.5)碳酸盐化的BOF炉渣,粒径小于30.5毫米。

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