The computational fluid dynamics analysis and optimisation of process vessels used in the manufacture of military propellants and high explosives

摘要

This research focuses on the computational fluid dynamics modelling and simulation of the existing reactors and mixing tanks employed by the Australian Defence Industries to manufacture military propellants for gun projectiles and small rockets; high explosives for naval gun projectiles and aerial bombs. The main objective of this research is to gain a thorough understanding of these process vessels via research and to provide recommendations to improve their performance. Reactors and mixing tanks were chosen as the test unit operations because although they contribute significantly to the manufacturing process, reactors have frequently been poorly understood or in the case of mixing tanks, taken for granted. Consequently, there is a lack of comprehensive knowledge to support successful operations of these process vessels. In addition, this research also recommends using photocatalysis technology to destroy liquid wastes produced from such manufacturing activities.For each product, a full characterisation was provided that included detailed theoretical analyses that presents a unique insight into the hydrodynamics occurring in these process vessels. The credibility of theoretical predictions was demonstrated via qualitative and quantitative validation using particle image velocimetry. Results from characterisation showed that the reactors and mixing tanks employed in the manufacture of military propellants, high explosives or aerial bombs were operating at sub-optimum conditions. To tackle this shortcoming, four ideal geometrical configurations that promised optimum performance were proposed for each of the test studies. These included a designer reactor for the manufacture of military propellants and effective mixing tanks for suspending high explosive particles, blending different high explosives and for manufacturing aerial bombs. The correct implementation of these recommendations will provide an optimum operation that achieves high product throughput and concurrently reduces reject rate.Research was also conducted to formulate a set of multipurpose design guidelines for a suspension mixing tank. The design template created from the results will provide valuable information to researchers across industries in their quest to optimise any unit suspension mixing tank operated on the principle of mechanical agitation. Finally, modelling of reactive species was conducted on a laboratory-scale photoreactor, involving physical experiments to destroy toxic effluent aqueous phase.