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Devulcanization and recycling of waste automotive EPDM rubber powder by using shearing action and chemical additive

机译:利用剪切作用和化学添加剂对汽车废EPDM橡胶粉进行脱硫和回收

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摘要

In automotive applications, ethylene-propylene-diene rubber (EPDM) is used to manufacture various components and therefore recycling scrap rubber is a major issue. The primary aim of this study was to develop a new method for devulcanizing waste automotive EPDM rubber powder by using shearing action and chemical additive and recycle the devulcanized powder. A semi-industrial twin screw extruder with a shearing action and reactor along with 2-mercaptobenzothiazole-disulfide (MBTS) chemical were used to devulcanize the waste powder at two different feed screw speeds and main rotor speeds at a constant temperature of 220°C. To recycle the devulcanized powder, different amounts of the devulcanized powder were mixed with a commercial EPDM-based automotive rubber strips compound to produce blends. The blends, commercial compound and devulcanized powder were cured with a semi-efficient (SEV) vulcanization system and their viscosity, cure and mechanical properties measured. For the blends, the Mooney viscosity was unchanged with 40 wt%, crosslink density with 20 wt%, tensile strength and elongation at break with 10 wt%, and compression set with 20 wt% of the devulcanized powder. Interestingly, the hardness benefitted from 50 wt% of the devulcanized powder in the blends. The scorch and optimum cure times shortened and the cure rate index rose when the loading of the devulcanized powder in the blends was raised. This new method offered a major new route for devulcanizing and recycling the waste powder.
机译:在汽车应用中,乙烯-丙烯-二烯橡胶(EPDM)用于制造各种组件,因此回收废旧橡胶是一个主要问题。这项研究的主要目的是开发一种利用剪切作用和化学添加剂将汽车废EPDM橡胶粉脱硫的新方法,并将其循环利用。使用具有剪切作用和反应器的半工业双螺杆挤出机以及2-巯基苯并噻唑-二硫化物(MBTS)化学药品,以两种不同的进料螺杆速度和主转子速度在220°C的恒定温度下对废粉进行脱硫。为了再循环脱硫粉末,将不同量的脱硫粉末与基于商业EPDM的汽车橡胶条化合物混合以产生共混物。共混物,市售化合物和脱硫粉末用半高效(SEV)硫化系统固化,并测量其粘度,固化和机械性能。对于共混物,门尼粘度保持不变,为40重量%,交联密度为20重量%,拉伸强度和断裂伸长率为10重量%,压缩固化率为20重量%的脱硫粉末。有趣的是,硬度得益于混合物中50%(重量)的脱硫粉末。当共混物中增加了脱硫粉末的量时,焦烧时间和最佳固化时间缩短,固化速率指数上升。这种新方法为废粉的脱硫和再循环提供了一条重要的新途径。

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