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Growth-substrate induced performance degradation in chemically synthesized monolayer MoS2ᅠfield effect transistors

机译:化学合成的单层MoS2 ᅠ场效应晶体管中生长衬底引起的性能下降

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摘要

We report on the electronic transport properties of single-layer thick chemical vapor deposition (CVD) grown molybdenum disulfide (MoS2) field-effect transistors (FETs) on Si/SiO2 substrates. MoS2 has been extensively investigated for the past two years as a potential semiconductor analogue to graphene. To date, MoS2 samples prepared via mechanical exfoliation have demonstrated field-effect mobility values which are significantly higher than that of CVD-grown MoS2. In this study, we will show that the intrinsic electronic performance of CVD-grown MoS2 is equal or superior to that of exfoliated material and has been possibly masked by a combination of interfacial contamination on the growth substrate and residual tensile strain resulting from the high-temperature growth process. We are able to quantify this strain in the as-grown material using pre- and post-transfer metrology and microscopy of the same crystals. Moreover, temperature-dependent electrical measurements made on as-grown and transferred MoS2 devices following an identical fabrication process demonstrate the improvement in field-effect mobility.
机译:我们报告了在Si / SiO2衬底上生长的单层厚化学气相沉积(CVD),二硫化钼(MoS2)场效应晶体管(FET)的电子传输特性。在过去的两年中,MoS2作为一种潜在的石墨烯半导体类似物已被广泛研究。迄今为止,通过机械剥离制备的MoS2样品显示出的场效应迁移率值明显高于CVD生长的MoS2。在这项研究中,我们将显示CVD生长的MoS2的固有电子性能与剥离材料的固有电子性能相同或更高,并且可能被生长衬底上的界面污染和高应力导致的残余拉伸应变共同掩盖了。温度增长过程我们能够使用转移前和转移后的计量学以及相同晶体的显微镜在成长期的材料中对该菌株进行定量。此外,采用相同的制造工艺在成年和转移的MoS2器件上进行的随温度变化的电气测量证明了场效应迁移率的提高。

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