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Toroid Cavity Detectors for High-Resolution NMR Spectroscopy and Rotating Frame Imaging: Capabilities and Limitations

机译:用于高分辨率NMR光谱和旋转框架成像的环形腔检测器:功能和局限性

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摘要

The capabilities of toroid cavity detectors for simultaneousudrotating frame imaging and NMR spectroscopy have been investigatedudby means of experiments and computer simulations. The following problems are described: (a) magnetic field inhomogeneity and subsequent loss of chemical shift resolution resulting from bulk magnetic susceptibility effects, (b) image distortions resulting from off-resonance excitation and saturation effects, and (c) distortion of lineshapes and images resulting from radiation damping. Also, special features of signal analysis including truncation effects and the propagation of noise are discussed. B0 inhomogeneity resulting from susceptibility mismatch is a serious problem for applications requiring high spectral resolution. Image distortions resulting from off-resonance excitation are not serious within the rather narrow spectral range permitted by the RF pulse lengths required to read out the image. Incomplete relaxation effects are easily recognized and can be avoided. Also, radiation damping produces unexpectedly small effects because of selfcancellation of magnetization and short free induction decay times. The results are encouraging, but with present designs only modest spectral resolution can be achieved.
机译:通过实验和计算机仿真,研究了环形腔探测器同时进行 uduting帧成像和NMR光谱的能力。描述了以下问题:(a)磁场不均匀性以及随后由于整体磁化率效应引起的化学位移分辨率的损失;(b)由非共振激发和饱和效应导致的图像失真;以及(c)线形和图像的失真辐射衰减造成的。此外,还讨论了信号分析的特殊功能,包括截断效应和噪声传播。对于需要高光谱分辨率的应用,由磁化率不匹配导致的B0不均匀性是一个严重的问题。在读取图像所需的RF脉冲长度所允许的相当窄的光谱范围内,由失谐激发引起的图像失真并不严重。不完全的松弛效果很容易识别,可以避免。而且,由于磁化作用的自抵消和较短的自由感应衰减时间,辐射阻尼产生了意想不到的小影响。结果令人鼓舞,但是使用当前设计只能实现适度的光谱分辨率。

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