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Ligand influence on nanoparticle agglomeration in flow

机译:配体对流动中纳米颗粒团聚的影响

摘要

Having emerged from basic science, nanoparticles are now applied in many fields of science and technology. Agglomeration is ubiquitous and occurs, often inadvertently, in the formulation of particle-polymer mixtures, during the chemical functionalisation of nanoparticles and even during storage.This dissertation outlines recent studies on the agglomeration behaviour of different gold nanoparticle types. A modular fluidic system was specifically designed to perform the experiments. It enables the preparation of a steady flow of stable or unstable nanoparticle samples. This allows to observe different steps of a time-dependant process in steady state over practically arbitrary times in flow.These capabilities are used in this research to investigate the agglomeration of destabilised aqueous gold nanoparticles, reassess the solvent induced self-assembly of unpolar gold nanoparticles and examine the shear-assisted orientation of gold nanowires. The performance of the system is demonstrated and new insights on the influence of solvent conditions, temperature and the flow field are presented. The relevant process parameters as well as the microscopic interactions responsible for the structure formation mechanisms are discussed.
机译:纳米粒子已经从基础科学中脱颖而出,现已应用于许多科学和技术领域。团聚现象无处不在,通常在颗粒-聚合物混合物的配制过程中,在纳米粒子的化学功能化过程中甚至在储存过程中无意中发生。专门设计了模块化流体系统来执行实验。它能够制备稳定或不稳定的纳米颗粒样品的稳定流。这允许在几乎任意流动时间内观察稳态过程中时变过程的不同步骤。这些功能用于研究不稳定的金纳米颗粒的团聚,重新评估溶剂诱导的非极性金纳米颗粒的自组装并研究金纳米线的剪切辅助取向。演示了系统的性能,并提出了对溶剂条件,温度和流场影响的新见解。讨论了相关的工艺参数以及负责结构形成机理的微观相互作用。

著录项

  • 作者

    Gerstner Dominik;

  • 作者单位
  • 年度 2016
  • 总页数
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类

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