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Nonequilibrium dynamics of dense gas under tight confinement

机译:密闭条件下高浓度气体的非平衡动力学

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摘要

The force-driven Poiseuille flow of dense gases between two parallel plates is investigated through the numerical solution of the generalized Enskog equation for two-dimensional hard discs. We focus on the competing effects of the mean free path λ, the channel width L, and the disc diameter σ. For elastic collisions between hard discs, the normalised mass flow rate in the hydrodynamic limit increases with L/σ for a fixed Knudsen number (defined as Kn = λ/L), but is always smaller than that predicted by the Boltzmann equation. Also, for a fixed L/σ, the mass flow rate in the hydrodynamic flow regime is not a monotonically decreasing function of Kn but has a maximum when the solid fraction is about 0.3. Under ultra-tight confinement the famous Knudsen minimum disappears, and the mass flow rate increases with Kn, and is larger than that predicted by the Boltzmann equation in the free-molecular flow regime; for a fixed Kn, the smaller the L/σ, the larger the mass flow rate. In the transitional flow regime, however, the variation of the mass flow rate with L/σ is not monotonic for a fixed Kn: the minimum mass flow rate occurs at L/σ ≈ 2 ∼ 3. For inelastic collisions, the energy dissipation between the hard discs always enhances the mass flow rate. Anomalous slip velocity is also found, which decreases with increasing Knudsen number. The mechanism for these exotic behaviour is analysed.
机译:通过二维磁盘广义Enskog方程的数值解,研究了力驱动的Poiseuille致密气体在两个平行板之间的流动。我们关注平均自由路径λ,通道宽度L和光盘直径σ的竞争效应。对于硬盘之间的弹性碰撞,对于固定的Knudsen数(定义为Kn =λ/ L),流体动力学极限中的归一化质量流率随L /σ增大,但始终小于Boltzmann方程所预测的质量流率。同样,对于固定的L /σ,流体动力流态中的质量流速不是Kn的单调递减函数,而当固体分数约为0.3时具有最大值。在超密闭条件下,著名的克努森最小值消失,质量流量随Kn的增加而增加,并且大于自由分子流态下玻耳兹曼方程所预测的质量流量;对于固定的Kn,L /σ越小,质量流量越大。然而,在过渡流态下,对于固定的Kn,质量流率随L /σ的变化不是单调的:最小质量流率发生在L /σ≈2〜3。对于非弹性碰撞,之间的能量耗散硬盘始终可以提高质量流量。还发现了异常的滑移速度,其随着克努森数的增加而减小。分析了这些外来行为的机制。

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