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Thermomechanical analysis of porous solid oxide fuel cell by using peridynamics

机译:多孔动力学法对多孔固体氧化物燃料电池的热力学分析

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摘要

Solid oxide fuel cell (SOFC) is widely used in hybrid marine propulsion systems due to its high power output, excellent emission control and wide fuel suitability. However, the operating temperature in SOFC will rise up to 800–1000 ℃ due to redox reaction among hydrogen and oxygen ions. This provides a suitable environment for ions transporting through ceramic materials. Under such operation temperatures, degradation may occur in the electrodes and electrolyte. As a result, unstable voltage, low capacity and cell failure may eventually occur. This study presents thermomechanical analysis of a porous SOFC cell plate which contains electrodes, electrolytes and pores. A microscale specimen in the shape of a plate is considered in order to maintain uniform temperature loading and increase the accuracy of estimation. A new computational technique, peridynamics, is utilized to calculate the deformations and stresses of the cell plate. Moreover, the crack formation and propagation are also obtained by using peridynamics. According to the numerical results, damage evolution depends on the electrolyte/electrode interface strength during the charging process. For weak interface strength case, damage emerges at the electrode/electrolyte interface. On the other hand, for stronger interface cases, damage emerges on pore boundaries especially with sharp corner.
机译:固体氧化物燃料电池(SOFC)由于其高功率输出,出色的排放控制和广泛的燃料适用性而广泛用于混合动力船舶推进系统。但是,由于氢和氧离子之间的氧化还原反应,SOFC中的工作温度将上升到800-1000℃。这为离子通过陶瓷材料传输提供了合适的环境。在这样的操作温度下,电极和电解质中可能发生降解。结果,最终可能发生电压不稳定,容量低和电池故障。这项研究提出了一种多孔SOFC电池板的热力学分析,该电池板包含电极,电解质和孔。为了保持均匀的温度负荷并提高估计的准确性,考虑使用板状的微型标本。一种新的计算技术,即周边动力学,用于计算细胞板的变形和应力。此外,裂纹的形成和扩展也可以通过使用动力学来获得。根据数值结果,损伤的发展取决于充电过程中电解质/电极界面的强度。对于弱界面强度的情况,在电极/电解质界面处会出现损坏。另一方面,对于更坚固的界面情况,损坏会出现在孔边界处,尤其是尖锐的拐角处。

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