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Characteristics of GaN-based light emitting diodes with different thicknesses of buffer layer grown by HVPE and MOCVD

机译:通过HVPE和MOCVD生长具有不同厚度缓冲层的GaN基发光二极管的特性

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摘要

GaN-based light emitting diodes (LEDs) have been fabricated on sapphire substrates with different thicknesses of GaN buffer layer grown by a combination of hydride vapor phase epitaxy and metalorganic chemical vapor deposition. We analyzed the LED efficiency and modulation characteristics with buffer thicknesses of 12 µm and 30 µm. With the buffer thickness increase, cathodoluminescence hyperspectral imaging shows that the dislocation density in the buffer layer decreases from ∼1.3X10 8 cm-2 to∼1.0 X 10 8 cm-2, and Raman spectra suggest that the compressive stress in the quantum wells is partly relaxed, which leads to a large blue shift in the peak emission wavelength of the photoluminescence and electroluminescent spectra. The combined effects of the low dislocation density and stress relaxation lead to improvements in the efficiency of LEDs with the 30 µm GaN buffer, but the electrical-to-optical modulation bandwidth is higher for the LEDs with the 12 µm GaN buffer. A rate equation analysis suggests that defect-related nonradiative recombination can help increase the modulation bandwidth but reduce the LED efficiency at low currents, suggesting that a compromise should be made in the choice of defect density.
机译:基于GaN的发光二极管(LED)已被制造在具有不同厚度的GaN缓冲层的蓝宝石衬底上,其中GaN缓冲层是通过氢化物气相外延和金属有机化学气相沉积的组合而生长的。我们分析了缓冲厚度分别为12 µm和30 µm的LED效率和调制特性。随着缓冲层厚度的增加,阴极发光高光谱成像显示缓冲层中的位错密度从约1.3X10 8 cm-2降低至约1.0 X 10 8 cm-2,拉曼光谱表明,量子阱中的压应力为部分松弛,导致光致发光和电致发光光谱的峰值发射波长出现较大的蓝移。低位错密度和应力松弛的综合作用可提高具有30 µm GaN缓冲器的LED的效率,但具有12 µm GaN缓冲器的LED的电光调制带宽更高。速率方程分析表明,与缺陷有关的非辐射复合可帮助增加调制带宽,但在低电流下降低LED效率,这表明在选择缺陷密度时应做出妥协。

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