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The chemical compatibility of thermoplastic hose used in umbilicals

机译:用于脐带的热塑性软管的化学相容性

摘要

The effects of solvents and temperature on thermoplastic hose for umbilical service are reported in this paper. Accelerated ageing tests were undertaken and analysed by gravimetric, mechanical and calorimetric measurements. Water and methanol were found to cause physical degradation of the polymer, mainly at high temperatures, whereas xylene caused chemical degradation, which increased with increasing temperature. The activation energy for the alpha-process within polyethylene (PE) was found to be 96.3 kJ mol(-1) for un-aged PE and increased to 106.2 kJ moll after 64 days of ageing in water at 100degreesC. The changes in activation energy will be used to make a life-time prediction of umbilical lines
机译:本文报道了溶剂和温度对用于脐带热塑软管的影响。进行了加速老化测试,并通过重量,机械和量热测量进行了分析。发现水和甲醇主要在高温下引起聚合物的物理降解,而二甲苯引起化学降解,其随温度升高而增加。对于未老化的PE,在聚乙烯(PE)中进行Alpha处理的活化能为96.3 kJ mol(-1),在100°C的水中老化64天后,其活化能提高至106.2 kJ摩尔。活化能的变化将用于预测脐带线的寿命

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