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The influence of coupling agent, fibre sizing and matrix degradation on the interfacial shear strength between carbon fibre and polypropylene

机译:偶联剂,纤维上浆和基体降解对碳纤维与聚丙烯界面剪切强度的影响

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摘要

The interface strength between carbon fibre (CF) and polypropylene (PP) was characterised using the microbond test. The eect of removing the sizing from the fibres, as well as introducing a maleic anhydride grafted polypropylene (MAPP) coupling agent were investigated. The polymer was found to degrade when prepared under atmospheric conditions, and therefore droplets were formed in a nitrogen purged oven for subsequent studies. The removal of the sizing from the fibre using pyrolysis and solvolysis techniques had little influence on the apparent interfacial shear strength (IFSS), suggesting that the IFSS for recovered fibres is similar to that of virgin fibres. Introducing a maleic anhydride coupling agent at 2wt% had the largest influence on the interface strength, increasing it by 320%.
机译:碳纤维(CF)和聚丙烯(PP)之间的界面强度使用微粘结测试进行了表征。研究了从纤维上去除胶料以及引入马来酸酐接枝聚丙烯(MAPP)偶联剂的效果。发现该聚合物在大气条件下制备时会降解,因此会在氮气吹扫的烘箱中形成液滴,以进行后续研究。使用热解和溶剂分解技术从纤维中去除上浆对表观界面剪切强度(IFSS)几乎没有影响,这表明回收纤维的IFSS与原始纤维相似。引入2wt%的马来酸酐偶联剂对界面强度的影响最大,增加320%。

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