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Investigation of Catalytic Effect Nitrite on Electrochemical Reduction of Cobalt Dimethylglyoxime Complex by Polarographic and Voltammetric Techniques

机译:亚硝酸盐对极谱和伏安技术电化学还原钴二甲基乙二肟配合物的催化作用研究

摘要

The voltammetric and polarographic behaviour of Cobalt Dimethylglyoxime (Co-DMG) complex on audhanging mercury drop electrode (HMDE) and static mercury drop electrode (SMDE) has been studiedudby several techniques including Square wave voltammetry (SWV), Differential pulse polarographyud(DPP) and stripping techniques. Polarographic and voltammetric curves recorded at HMDE andudSMDE provide information about electrode reaction mechanism. Catalytic effect of nitrite on theudelectrochemical reduction mechanism of the complex have been explained.
机译:通过方波伏安法,微分脉冲极谱法等多种技术研究了二甲基乙二肟钴(Co-DMG)配合物在悬垂式汞滴电极(HMDE)和静态汞滴电极(SMDE)上的伏安和极谱行为。 ud(DPP)和剥离技术。 HMDE和 udSMDE记录的极谱和伏安曲线提供了有关电极反应机理的信息。已经解释了亚硝酸盐对配合物的 ud电化学还原机理的催化作用。

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