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Characterization and immobilization of white slag from secondary metallurgical processes in cementitious composites

机译:水泥基复合材料二次冶金过程中白渣的表征与固定化

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摘要

The fundamental objective of this study was to define such a cement composite with the addition ofudwhite (ladle) slag, which will provide functionality for selected purposes and furthermore, prevent theudleaching of toxic elements into the environment. The recovery (recycling) of secondary metallurgicaludslags from stainless steel production has an important synergistic impact on the environment. In thisudstudy, detailed characterization of slag derived from two different ladle refining processes of stainlessudsteel production has been performed. In order to assess its potential for use as a supplementaryudcementitious material, slag cement composites as well as slag itself were investigated. A comparativeudstudy of reference cement composites and cement composites to which a conventional supplementaryudcementitious material (limestone filler) had been added, was also performed. The results showed thatudthe slag contains hydraulic phases to a total amount of about 50 %. Calcium aluminates are theudpredominant constituents. In the case of slag cement composites, a larger degree of strengthuddevelopment was observed in comparison to the cement composite with the addition of limestoneudfiller. This was attributed to the larger proportion of hydration products formed in the slag cementudcomposite. The environmental impact of cement composite with the addition of the investigated slagudwas further evaluated. The results revealed that chromium was immobilized in the cement compositesudwith the addition of slag. Cr(VI) content originating from the cement was also appreciably reduced byudthe added slag, which thus had significant positive environmental effects. The stabilization process isudcontrolled by the reducing and hydraulic properties of the slag. It was demonstrated that the presenceudof the investigated slag in cement composites does not influence its durability. The investigated whiteud(ladle) slag can be implemented in cement composites as supplementary cementitious material.
机译:这项研究的基本目标是定义一种添加了 udwhite(钢包)矿渣的水泥复合材料,这将为选定的目的提供功能,并防止有毒元素向环境中渗出。不锈钢生产中二级冶金渣的回收(再循环)对环境具有重要的协同作用。在本研究中,对不锈钢/钢生产的两种不同钢包精炼过程中产生的炉渣进行了详细的表征。为了评估其用作辅助/胶结材料的潜力,对矿渣水泥复合材料以及矿渣本身进行了研究。还进行了参考水泥复合材料和水泥复合材料的比较研究,其中已添加了常规的补充/增补材料(石灰石填料)。结果表明,渣中所含的水相总量约为50%。铝酸钙是主要成分。在矿渣水泥复合材料的情况下,与添加石灰石填充剂的水泥复合材料相比,观察到更大的强度发展。这归因于在矿渣水泥复合物中形成的水​​合产物的比例较大。进一步评估了掺有所研究的矿渣的水泥复合材料对环境的影响。结果表明,在添加了矿渣的情况下,铬被固定在水泥复合材料中。水泥渣还可以显着降低水泥中的Cr(VI)含量,因此对环境具有明显的积极影响。稳定过程由矿渣的还原性和水硬性控制。结果表明,所研究的水泥复合物中矿渣的存在不会影响其耐久性。所研究的白/渣(lad子)矿渣可以在水泥复合材料中用作辅助胶凝材料。

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    Zalar Serjun Vesna;

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