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On the beating of reinforcement pulp

机译:关于补强浆的跳动

摘要

The aim of this work was to gain a better understanding of the effect of reinforcement pulp beating on the strength of mechanical pulp-dominated paper. The main purpose of reinforcement pulp beating is to improve the runnability of paper. The first objective of this study was to maximize the runnability related strength properties by beating. It was assumed that the flaw-resisting ability of paper correlates with the runnability of the dry paper web. In-plane fracture properties were assumed to describe the flaw-resisting ability. The second objective was to understand the mechanism how beating affects paper strength and structure (e.g. the size of the fracture process zone).It was found that the reinforcement pulp ranking and optimisation of beating depend on the criteria used. The selection of critical strength properties affects the pulp ranking - sometimes different methods give opposite results (e.g. neutral sulphite vs. kraft). It was found that beating does not increase the in-plane fracture energy of mechanical pulp-dominated paper. Fracture toughness and elastic breaking strain increase only a little. However, tensile strength, elastic modulus and z-directional strength properties increase. It was concluded that beating does not significantly improve the flaw-resisting ability of mechanical pulp-dominated paper, while the strength of unflawed paper does increase.It was found that the fracture properties of mixture sheets cannot be estimated based only on fracture properties of pure components. The additivity behaviour of fracture properties was strongly non-linear. The fracture energy of pulp mixtures seems to correlate mainly with the average fibre length (and not with the beating level). Beating increases the fracture energy per fracture zone area in the pure chemical pulp sheets but not in the mixture sheets. Evidently beating does not increase the energy needed to open interfibre bonds in mechanical pulp-dominated paper.The results can be explained by the beating induced increase in both interfibre bonding and fibre segment activation. It was also found necessary to divide bonding into in-plane and out-of-plane components. The results largely support the activation theory originally presented in the 1960's. However, no direct measurement of activation was used in this study. Low-freeness mechanical pulp seems to have as high (in-plane) interfibre bonding as but lower activation than beaten reinforcement pulp. Therefore reinforcement pulp beating improves bonding-related properties such as elastic breaking strain or in-plane fracture energy only marginally. On the other hand, properties strongly dependent on activation, such as elastic modulus and tensile strength, are increased by reinforcement pulp beating.
机译:这项工作的目的是更好地理解增强浆打浆对机械浆占主导地位的纸的强度的影响。增强纸浆打浆的主要目的是提高纸张的运行性能。这项研究的第一个目标是通过殴打最大化与可运行性相关的强度特性。假定纸张的抗缺陷能力与干纸幅的可运行性相关。假定面内断裂性能描述了抗裂能力。第二个目的是了解打浆如何影响纸张强度和结构(例如断裂过程区的大小)的机理,发现补强浆的等级和打浆的优化取决于所使用的标准。临界强度特性的选择会影响纸浆等级-有时不同的方法会得出相反的结果(例如中性亚硫酸盐和牛皮纸)。发现打浆不会增加以机械纸浆为主的纸的面内断裂能。断裂韧性和弹性断裂应变仅增加一点。但是,抗张强度,弹性模量和z向强度特性增加。结论是,打浆并不能显着提高以机械纸浆为主导的纸张的抗瑕疵能力,而无瑕疵纸张的强度却确实有所提高。发现混合纸张的断裂性能不能仅根据纯纸的断裂性能来估算组件。断裂特性的加和行为是强烈非线性的。纸浆混合物的断裂能似乎主要与平均纤维长度相关(而不与打浆水平相关)。打浆增加了纯化学纸浆片中的每个断裂带区域的断裂能,但没有增加混合物片中的断裂能。明显地,打浆并不会增加在机械纸浆为主的纸中打开纤维间键所需的能量。结果可以用纤维间键合和纤维段活化的跳动引起的增加来解释。还发现有必要将粘结分为面内和面外组件。结果很大程度上支持了1960年代最初提出的激活理论。但是,在这项研究中,没有直接测量激活。低游离度机械浆似乎具有与打浆增强浆一样高的(面内)纤维间粘合力,但活化度较低。因此,增强纸浆打浆仅略微改善了与粘合有关的性能,例如弹性断裂应变或面内断裂能。另一方面,增强纸浆的打浆增加了强烈依赖于活化的性能,例如弹性模量和拉伸强度。

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    Hiltunen Eero;

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  • 年度 2003
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