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Impregnation, vapor phase and methanol as means of intensifying the softwood kraft pulping process

机译:浸渍,气相和甲醇作为强化软木牛皮纸制浆过程的手段

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摘要

The objective of the research was to find ways to shorten the cooking time, i.e. intensify the kraft pulping process. The reason for undertaking such a study lies in the long standing trend of ever increasing reactor size in the kraft pulping industry. The huge digester size in use presently has lead to severe problems in understanding the behavior of the chip column inside the digester. An intensified process with a drastically shorter pulping time would give a more manageable process and greater freedom in reactor design.The study was performed using a new experimental digester giving a much greater control over temperatures than what can be achieved with other types of digesters. This enabled experiments that clarify the impact of impregnation, heat-up time, cooking temperature and cooking time to a greater degree than what has been possible earlier. The research on actual intensification centered on understanding the impact of impregnation and the impact of alcohols (methanol) on the overall rate of pulping.This research supports earlier research that shows how the cooking time can be shortened using alcohols as additives in pulping. It also supports results showing that a fast process can be achieved by using impregnation with high concentrations of cooking chemicals followed by a cooking stage performed with direct steam heating. The fact that the effects work in synergy so that the fastest pulping process identified was one that employed high concentration impregnation followed by heating using methanol steam is a new finding. The decrease in cooking time compared to a conventional liquid phase batch process without proper impregnation is close to 70%.The present research was aimed only at shortening the cooking time and does not address questions related to actual digester and process design and economical feasibility of the process. Especially the regeneration of cooking chemicals and methanol are an area that will need further study before such question can be addressed.
机译:研究的目的是找到缩短烹饪时间的方法,即加强牛皮纸制浆过程。进行这种研究的原因在于牛皮纸制浆工业中反应器尺寸不断增加的长期趋势。当前使用的巨大消化器尺寸导致在理解消化器内部芯片柱的行为方面出现严重问题。制浆时间大大缩短的强化工艺将使工艺更易于管理,并具有更大的反应器设计自由度。这项研究是使用新型实验性蒸煮器进行的,与其他类型的蒸煮器相比,该蒸煮器对温度的控制要大得多。这使实验能够比以前更清楚地阐明浸渍,加热时间,烹饪温度和烹饪时间的影响。实际强化研究的重点是了解浸渍的影响以及醇类(甲醇)对制浆总速率的影响。这项研究支持早期研究,该研究表明如何在制浆中使用醇类添加剂来缩短烹饪时间。它还支持以下结果:通过在高浓度的烹饪化学品中进行浸渍,然后通过直接蒸汽加热进行的烹饪阶段,可以实现快速加工。新的发现是,这些效果协同作用,因此确定的最快制浆过程是先进行高浓度浸渍,然后再用甲醇蒸汽加热的过程。与没有适当浸渍的传统液相间歇法相比,蒸煮时间的减少接近70%。本研究仅旨在缩短蒸煮时间,并未解决与实际蒸煮器和工艺设计以及该炉的经济可行性有关的问题。处理。尤其是烹饪化学品和甲醇的再生是一个需要进一步研究才能解决的问题。

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    Enqvist Eric;

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  • 年度 2006
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