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Optimization of activator solution and heat treatment of ground lignite type fly ash geopolymers

机译:褐煤型粉煤灰地质聚合物活化剂溶液的优化和热处理

摘要

Geopolymers are inorganic polymers which can be produced by the reaction between silico aluminate oxides and alkali silicates in alkaline medium. Materials containing silica and alumina compounds are suitable for geopolymer production. These can be primary materials or industrial wastes, i. e. fly ash, metallurgical slag and red mud. ud In this paper, the results of the systematic experimental series are presented which were udcarried out in order to optimize the geopolymer preparation process. Fly ash was ground for uddifferent residence time (0, 5, 10, 30, 60 min) in order to investigate the optimal specific udsurface area. NaOH activator solution concentration also varied (6, 8, 10, 12, 14 M). udFurthermore, sodium silicate was added to NaOH as a network builder solution. In this last udserie different heat curing temperatures (30, 60, 90°C) were also applied. After seven days of udageing the physical properties of the geopolymer(compressive strength and specimen uddensity)were measured. Chemical leaching tests on the rawmaterial and the geopolymers were udcarried out to determine the elements which can be mobilized by different leaching solutions. It udwas found that the above mentioned parameters (fly ash fineness, molar concentration and udcomposition of activator solution, heat curing) has great effect on the physical and chemical udproperties of geopolymer specimens. Optimal conditions were as follows: specific surface area udof the fly ash above 2000 cm2/g, 10 M NaOH, 30o C heat curing temperature which resulted in 21 MPa compressive strength geopolymer.
机译:地质聚合物是无机聚合物,可以通过硅铝酸盐氧化物和碱金属硅酸盐在碱性介质中的反应生产。包含二氧化硅和氧化铝化合物的材料适用于地质聚合物的生产。这些可以是主要材料或工业废物,即e。粉煤灰,冶金渣和赤泥。 ud本文介绍了系统的实验结果,并进行了研究,以优化地聚合物的制备过程。为了研究最佳的比表面积,粉煤灰被研磨了不同的停留时间(0、5、10、30、60分钟)。 NaOH活化剂溶液浓度也有所不同(6、8、10、12、14 M)。此外,将硅酸钠添加到NaOH中作为网络助洗剂溶液。在这最后的方法中,还采用了不同的热固化温度(30、60、90°C)。整理7天后,测量了地质聚合物的物理性质(抗压强度和试样的密度)。对原材料和地质聚合物进行化学浸提测试,以确定可以通过不同浸提溶液迁移的元素。我们发现上述参数(粉煤灰的细度,摩尔浓度和活化剂溶液的组成,热固化)对地质聚合物样品的物理和化学性能有很大的影响。最佳条件如下:粉煤灰比表面积大于2000 cm2 / g,10 M NaOH,30°C热固化温度,其抗压强度为21 MPa。

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