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Determination of migration monomer styrene from GPPS (general purpose polystyrene) and HIPS (high impact polystyrene) cups to hot drinks

机译:测定从GPPS(通用聚苯乙烯)和HIPS(高抗冲聚苯乙烯)杯到热饮的迁移单体苯乙烯

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摘要

In this study, 162 samples were analysed for monomer styrene content with using high performance liquid chromatography (HPLC) method in hot tea, milk, cocoa milk. The monomer styrene content, expressed in μg/l of drink and the level of migration of styrene monomer were varied from 0.61 to 8.15 for hot tea, from 0.65 to 8.30 for hot milk, from 0.71 to 8.65 for hot cocoa milk in GPPS (general purpose polystyrene), from 0.48 to 6.85 for hot tea, from 0.61 to 7.65 for hot milk, from 0.72 to 7.78 for hot cocoa milk in HIPS (high performance polystyrene) cups in different temperatures and times. The estimated limit of detection of (HPLC) method for all samples was 0.001 mg/kg. There is linear regression for styrene monomer from 1 to 10 ng/ml. Several samples spiked with a known amount of styrene monomer. The results of the recovery in study for styrene monomer were determinate to be mean, 96.1 ± 1.92 to 99.7 ± 1.15%. The results of this study indicate that styrene monomer from polystyrene disposable into hot and fat drinks was migrated and this migration was highly dependent on fat content and temperature of drinks. The derived concentration of styrene monomer in this study was above the EPA (Environmental protection agency) recommended level, especially in MCLG (Maximum contaminant level goal) standard. More study is needed to further elucidate this finding.
机译:在这项研究中,使用高效液相色谱(HPLC)方法在热茶,牛奶,可可豆中分析了162个样品的单体苯乙烯含量。在GPPS中,以饮料的微克/升表示的单体苯乙烯含量和苯乙烯单体的迁移水平从热茶的0.61到8.15,从热牛奶的0.65到8.30,从热可可牛奶的0.71到8.65变化(一般)用途聚苯乙烯),在不同温度和时间下,在HIPS(高性能聚苯乙烯)杯子中,热茶从0.48至6.85,热牛奶从0.61至7.65,热可可牛奶从0.72至7.78。所有样品的(HPLC)方法检出限估计为0.001 mg / kg。苯乙烯单体从1到10 ng / ml线性回归。几个样品掺入了已知数量的苯乙烯单体。研究中苯乙烯单体的恢复结果确定为平均值,为96.1±1.92至99.7±1.15%。这项研究的结果表明,从一次性聚苯乙烯到热和脂肪饮料中的苯乙烯单体已经迁移,这种迁移高度依赖于饮料的脂肪含量和温度。这项研究中得出的苯乙烯单体浓度高于EPA(环境保护机构)建议的水平,尤其是在MCLG(最大污染物水平目标)标准中。需要更多的研究来进一步阐明这一发现。

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