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Elastic properties of polymeric Langmuir-Blodgett films studied using Brillouin light scattering.

机译:使用布里渊光散射研究的聚合物Langmuir-Blodgett薄膜的弹性性能。

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摘要

Brillouin light scattering (BLS) experiments have been performed on polymeric uniaxial Langmuir-Blogett (LB) films, whose preferred axes are in the plane of the film, to investigate their elastic properties. By assigning the spectral signals unambiguously, the whole set of the elastic constants and the indices of refraction were determined. As the monolayer thickness increased from 16.5 to 20.5 A, the elastic constants decreased and the refractive indices were not changed. These decreasing elastic constants were interpreted in terms of a superlattice model of the polymeric LB films. BLS coupled with surface-plasmon-polaritons was studied to not only enhance the Brillouin signal by more than a factor of 15, but also to study the hybridization of the dispersion relations between the guided modes of a CdA LB film and the Rayleigh-Sezawa modes of the supported Ag film coated on a prism. The Kretschmann ATR geometry was used. The angular dependence of the intensity of the surface-plasmon-polariton-enhanced BLS for a prism-metal-dielectic system was also studied.
机译:布里渊光散射(BLS)实验已在聚合物单轴Langmuir-Blogett(LB)薄膜上进行,其优选轴位于薄膜平面内,以研究其弹性性能。通过明确分配频谱信号,可以确定整个弹性常数和折射率。随着单层厚度从16.5 A增加到20.5 A,弹性常数降低并且折射率不变。这些降低的弹性常数是根据聚合物LB薄膜的超晶格模型来解释的。研究了BLS与表面等离子体激元极化子的结合,不仅使布里渊信号增强了15倍以上,而且还研究了CdA LB膜的导模与Rayleigh-Sezawa模之间的色散关系的杂交涂覆在棱镜上的支撑银膜的厚度。使用了Kretschmann ATR几何形状。还研究了棱镜-金属-介电系统的表面等离子体激元增强的BLS强度的角度依赖性。

著录项

  • 作者

    Lee Sukmock.;

  • 作者单位
  • 年度 1991
  • 总页数
  • 原文格式 PDF
  • 正文语种 en
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