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The Preparation of Manganese Dioxide by the Decomposition of Manganese Carbonate

机译:碳酸锰分解制备二氧化锰

摘要

The properties of MnO_2 which are made from the thermal decomposition of MnCO_3 in air at 5 atm have been compared with those of MnO_2 made from several other methods. The following experiments were made to examine of the properties of MnO_2 : the specific surface area by BET method, the quantity of decomposition of oxalic acid, the quantity of decomposition of hydrazine hydrosulfate and discharge capacity of the Leclanche cell. From the results of the examinations, it was found that the depolarization activity of MnO_2 for dry cell were in order as follows : from electrolytic method>from KMnO_4+HNO_3>from the other chemical processes and from the decomposition of MnCO_3 in the air at 5 atm>from the decomposition of MnCO_3 in atmospheric air>natural MnO_2.
机译:比较了由MnCO_3在5 atm的空气中热分解产生的MnO_2的特性与由其他几种方法制成的MnO_2的特性。进行以下实验以检查MnO_2的特性:BET法的比表面积,草酸的分解量,硫酸氢肼的分解量和Leclanche电池的放电容量。从检查结果中发现,MnO_2对干电池的去极化活性依次为:从电解法>从KMnO_4 + HNO_3>从其他化学过程以及从MnCO_3在空气中在5atm的分解>大气中MnCO_3的分解>天然MnO_2。

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