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Electric field induced reversible spreading of droplets into films on lubricant impregnated surfaces

机译:电场引起的液滴可逆地散布到润滑剂浸渍表面上的薄膜中

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摘要

Electric fields can be used to force a droplet to wet a solid surface using an applied voltage. However, significant hysteresis usually occurs associated with pinning forces at the contact line. Here, we report the forced spreading and subsequent retraction of droplets into liquid films in air on lubricant impregnated surfaces (also known as slippery liquid infused porous surfaces) where the contact line is completely mobile. We first confirm that we achieve a complete removal of hysteresis for the electrowetting of droplets above the saturation voltage. We then show that contact angle hysteresis can be reduced to less than 4° whilst retaining the ability to fully spread a droplet into a liquid film using an interface localized from liquid dielectrophoresis (dielectrowetting). In both cases, we find that the cosine of the contact angle has a quadratic dependence on applied voltage, consistent with previous theoretical expectations. Thus, our work demonstrates that fully reversible spreading encompassing a wide range of partial wetting droplet states and a film state can be achieved in air in a controllable manner with very low levels of hysteresis.
机译:电场可用于通过施加电压迫使液滴润湿固体表面。但是,通常会出现很大的磁滞现象,这与接触线上的钉扎力有关。在这里,我们报告了在接触线完全可移动的润滑剂浸渍表面(也称为滑液注入的多孔表面)上,空气中的液滴被迫散布并随后缩回到空气中的液膜中。我们首先确认,对于高于饱和电压的液滴电润湿,可以完全消除滞后现象。然后,我们表明接触角磁滞可以减小至小于4°,同时保留使用从液体介电电泳(介电润湿)定位的界面将液滴完全散布到液膜中的能力。在这两种情况下,我们都发现接触角的余弦对施加的电压具有二次依赖性,这与先前的理论预期一致。因此,我们的工作表明,可以在空气中以可控的方式实现具有非常低的滞后性的完全可逆的扩展,涵盖了广泛的部分润湿液滴状态和薄膜状态。

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