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Synthesis and Characterization ofudEuropium-Doped Zinc Sulphide (ZnS:Eu)udNano Particles: Nano Red Phosphor

机译:ud的合成与表征Do掺杂硫化锌(ZnS:Eu) ud纳米粒子:纳米红色荧光粉

摘要

A preliminary work on synthesis of Europium-doped Zinc sulphide nanophosphors is reported. The result showsudthat pure and well passivated ZnS:Eu3+ nano-particles were synthesized. The average particle sizes show thatudthe nano-particles are in the strong quantum confinement regime which is evident from the stoke-shift in theudabsorption spectrum and the broadening of the XRD diffraction peaks. Particles sizes determined from theudeffective mass approximation and hyperbolic band model show higher particle size distribution, as a result ofuda consequential failure of these models at very small size regime. The intensity of red light emitted from theudsynthesized ZnS:Eu nanophospors is size and site dependent. There is clear evidence that energy transferudfrom ZnS host to Eu3+ occurred but this emission has weak intensity.
机译:报道了synthesis掺杂硫化锌纳米磷光体合成的初步工作。结果表明合成了纯净且钝化良好的ZnS:Eu3 +纳米粒子。平均粒径表明,纳米颗粒处于强的量子约束状态,这从吸收光谱的斯托克频移和XRD衍射峰的展宽可以明显看出。由有效质量近似和双曲谱带模型确定的粒度显示出较高的粒度分布,这是由于这些模型在非常小的尺寸范围内会因此而失败。从合成不足的ZnS:Eu纳米磷光发出的红光强度取决于大小和位置。有明确的证据表明发生了从ZnS主体到Eu3 +的能量转移 ud,但是这种发射强度很弱。

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    Ahemen I; De Dilip Kumar;

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  • 年度 2013
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