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Plasmonic black gold by adiabatic nanofocusing and absorption of light in ultra-sharp convex grooves

机译:等离子黑金通过绝热纳米聚焦和超锋利凸形槽中的光吸收

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摘要

Excitation of localized and delocalized surface plasmon resonances can be used for turning excellent reflectors of visible light, such as gold and silver, into efficient absorbers, whose wavelength, polarization or angular bandwidths are however necessarily limited owing to the resonant nature of surface plasmon excitations involved. Nonresonant absorption has so far been achieved by using combined nano- and micro-structural surface modifications and with composite materials involving metal nanoparticles embedded in dielectric layers. Here we realize nonresonant light absorption in a well-defined geometry by using ultra-sharp convex metal grooves via adiabatic nanofocusing of gap surface plasmon modes excited by scattering off subwavelength-sized wedges. We demonstrate experimentally that two-dimensional arrays of sharp convex grooves in gold ensure efficient (87%) broadband (450-850 nm) absorption of unpolarized light, reaching an average level of 96%. Efficient absorption of visible light by nanostructured metal surfaces open new exciting perspectives within plasmonics, especially for thermophotovoltaics.
机译:激发局部和离域的表面等离子体激元共振可以用于将可见光的出色反射器(例如金和银)变成有效的吸收体,但是由于所涉及的表面等离子体激元的共振性质,其波长,偏振或角带宽必定受到限制。迄今为止,通过结合使用纳米结构和微结构的表面修饰以及涉及嵌入在介电层中的金属纳米颗粒的复合材料,已经实现了非共振吸收。在这里,我们通过使用超锐利的凸形金属凹槽,通过将亚波长大小的楔形物散射而激发的间隙表面等离子体激元模式的绝热纳米聚焦,实现了在明确定义的几何形状中的非共振光吸收。我们通过实验证明,金中锋利的凸凹槽的二维阵列可确保有效地(> 87%)宽带(450-850 nm)吸收非偏振光,达到平均96%的水平。纳米结构金属表面对可见光的有效吸收为等离激元学(特别是对于热光电学)打开了令人兴奋的新视野。

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