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Improvement of the durability of heat-treated wood against termites

机译:提高热处理木材对白蚁的耐久性

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摘要

Thermal modification is an attractive alternative to improve the decay durability and dimensional stability of wood. However, thermally modified wood is generally not resistant to termite attacks, limiting the field of application of such materials. One way to overcome this drawback is to combine thermal modification treatment with an additional treatment. One such treatment is the impregnation of a boron derivative associated with appropriate vinylic monomers, which takes advantage of the thermal treatment to polymerise these monomers for boron fixation. Using this strategy, we recently showed that an impregnation of borax (2 or 4% boric acid equivalent) dissolved in a 10% aqueous solution of polyglycerolmethacrylate followed by thermal treatment under nitrogen at 220°C protects wood from both termite and decay degradations, even after leaching. Additionally, wood samples treated with a 10% polyglycerolmethacrylate aqueous solution and subjected to thermal treatment at 220°C presented improved resistance to termites while avoiding boron utilization. Based on these results, we investigate the effect of impregnation with two types of vinylic monomers, which are already used in the presence of boron, followed by thermal treatments at different temperatures. We evaluate termite and decay durability of wood to evaluate if thermal modification associated with light chemical modification could be a solution for utilization of thermally modified materials in termite-infested areas. (Résumé d'auteur)
机译:热改性是改善木材的耐腐性和尺寸稳定性的有吸引力的替代方法。但是,热改性木材通常不能抵抗白蚁的侵袭,从而限制了这种材料的应用领域。克服该缺点的一种方法是将热改性处理与附加处理相结合。一种这样的处理是与适当的乙烯基单体缔合的硼衍生物的浸渍,其利用热处理来聚合这些单体以进行硼固定。使用这种策略,我们最近表明,将溶解在10%聚甲基丙烯酸甲基丙烯酸酯水溶液中的硼砂(2或4%的硼酸当量)浸渍,然后在220°C的氮气下进行热处理,可以保护木材免受白蚁和腐烂的损害,甚至浸出后。此外,用10%聚甲基丙烯酸甲基甘油酯水溶液处理并在220°C下进行热处理的木材样品在避免硼利用的同时,提高了对白蚁的抵抗力。基于这些结果,我们研究了在硼存在下已经使用的两种类型乙烯基单体的浸渍效果,然后在不同温度下进行热处理。我们评估木材的白蚁和腐烂耐久性,以评估与轻化学改性相关的热改性是否可以成为在白蚁出没地区利用热改性材料的解决方案。 (Résuméd'auteur)

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