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Preparation of Magnetic Carboxymethylchitosan Nanoparticles for Adsorption of Heavy Metal Ions

机译:磁性羧甲基壳聚糖纳米粒子的制备及其对重金属离子的吸附

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摘要

The remediation of metal and heavy metal contaminants from water ecosystems is a long-standing problem in the field of water management. The development of efficient, cost effective, and environmentally friendly natural polymer-based adsorbents is reported here. Magnetic chitosan (CS) and carboxymethylchitosan (CMC) nanocomposites have been synthesized by a simple one-step chemical coprecipitation method. The nanoparticles were assessed for the removal of Pb2+, Cu2+, and Zn2+ ions from aqueous solution. Kinetic and thermodynamic models were used to describe and understand the adsorption process of the ions onto the nanomaterials. The interactions between the ions and the biopolymer-based composites are reversible, which means that the nanoparticles can be regenerated in weakly acidic or EDTA containing solution without losing their activity and stability for water cleanup applications.
机译:水生态系统中金属和重金属污染物的修复是水管理领域的一个长期存在的问题。本文报道了开发高效,成本有效和环保的基于天然聚合物的吸附剂。磁性壳聚糖(CS)和羧甲基壳聚糖(CMC)纳米复合材料已通过简单的一步化学共沉淀法合成。评估纳米颗粒从水溶液中去除的Pb2 +,Cu2 +和Zn2 +离子。动力学和热力学模型用于描述和理解离子在纳米材料上的吸附过程。离子与基于生物聚合物的复合物之间的相互作用是可逆的,这意味着纳米颗粒可以在弱酸性或含EDTA的溶液中再生,而不会失去其在水净化应用中的活性和稳定性。

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