The interaction of water with graphene has been a quintessential example of hydrophobic interactions for many years. However, no reliable experimental or theoretical value exists for the water-graphene interaction energy. In the current document, the water-graphene interaction energy is explored using high-level ab initio methods. In addition, the water-graphene interaction energy is decomposed into its physical components in order to give further physical insight into the water-graphene interaction.Water is found in a variety of environments, ranging from small clusters to the bulk. Because of this, the development of accurate models capable of describing water in a wide range of environments has been an active area of research. In the second part of this document, the nature of the water--water interaction is explored and a new polarizable water model is presented.
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