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The depletion of ZDDP additives within marine lubricants and associated cylinder liner wear in RNLI lifeboat engines

机译:RNLI救生艇发动机中船用润滑油中ZDDP添加剂的消耗以及相关的气缸套磨损

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摘要

Previous work of authors indicated the wear of cylinder liners in marine engines of RNLI lifeboats due to the intense lubricant degradation identified by inductively coupled plasma and Fourier Transform Infrared spectroscopy techniques. In this paper, further analysis carried out to evaluate the effects of lubricant degradation on the actual cylinder liners installed in the Trent Class Lifeboat engines is presented. Surface characterisation of actual cylinder liner’s bore surface showed maximum wear near the top dead centre region compared to rest of the piston stroke. Wear in this region of the cylinder liner surface is controlled primarily by the protective film forming anti-wear additives in the lubricant which limit the direct surface contact between the piston rings and cylinder liner. The condition of zinc dialkyldithiophosphates anti-wear additives was analysed using the nuclear magnetic resonance spectroscopy. Tribology analysis was conducted to evaluate the tribological and boundary film forming performance of zinc dialkyldithiophosphates additives by simulating cylinder liner–piston ring contact near the top dead centre. To further understand the wear mechanisms of the cylinder liner, wear debris analysis (Analytical Ferrography) of lubricant samples was performed. Results revealed the depletion of phosphorus containing zinc dialkyldithiophosphates anti-wear additives as a function of the lubricant’s duty cycle within the marine engines and its effect on the tribological and boundary film forming performance of lubricants. Wear debris analysis showed the generation of ferrous debris potentially from the cylinder liners as a result of reduced anti-wear protection from the depleted zinc dialkyldithiophosphates additives during the tribological contact with piston rings and piston skirt region. These findings are useful to understand the lubricant degradation mechanisms which affect the functionality of cylinder liners, therefore allowing to plan the engine maintenance strategies.
机译:作者的先前工作表明,RNLI救生艇船用发动机的气缸套磨损是由于感应耦合等离子体和傅立叶变换红外光谱技术识别出的强烈润滑剂降解所致。在本文中,将进行进一步的分析以评估润滑油降解对安装在Trent级救生艇发动机上的实际气缸套的影响。与其余的活塞冲程相比,实际气缸套孔表面的表面特征显示出在上止点区域附近的最大磨损。汽缸套表面区域的磨损主要是由保护膜在润滑剂中形成抗磨添加剂控制的,该添加剂限制了活塞环和汽缸套之间的直接表面接触。使用核磁共振波谱分析了二烷基二硫代磷酸锌抗磨添加剂的条件。通过模拟上死点附近的气缸套-活塞环接触,进行了摩擦学分析,以评估二烷基二硫代磷酸锌添加剂的摩擦学和边界膜形成性能。为了进一步了解气缸套的磨损机理,对润滑剂样品进行了磨损碎片分析(铁谱分析)。结果表明,含磷的二烷基二硫代磷酸锌抗磨添加剂的消耗与船用发动机中润滑剂的工作循环有关,并且对润滑剂的摩擦学和边界膜形成性能有影响。磨损碎片分析显示,由于在与活塞环和活塞裙区的摩擦接触过程中,对耗尽的二烷基二硫代磷酸锌添加剂的抗磨损保护降低,因此可能从气缸套产生了铁屑。这些发现对于理解影响气缸套功能的润滑剂降解机理很有用,因此可以规划发动机维护策略。

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