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Extração, caracterização e aplicação do corante de urucum (Bixa orellana L.) no tingimento de fibras naturais

机译:胭脂红染料(Bixa orellana L.)的提取,表征及在天然纤维染色中的应用

摘要

The increasing demand for natural dyes in place of synthetic ones is justified by the non-toxicity or low toxicity of the former. The synthetic dyes are associated with diseases like cancer as well as when released in the environment takes longer to degrade and the intermediates could be still more toxic. The Annatto (Bixa Orellana L.) is a carotenoid and one of the more important natural dyes used in the food industry. In the form of dye, it represents nearly 70% of the world natural dye production and 90% in Brazil. In the present work, annatto seeds were used of the species peruana paulista, which had nearly 2.1% of bixin. The process of dye extraction with ethyl alcohol showed 4% of dye in the form of powder with particle diameter of 28mm. The extraction process did not alter the chemical composition of the dye, which was confirmed by the electronic spectrum of absorption. Dyeings were carried out with different mordents to study the total colour difference as well as the wash fastness properties and friction fastness properties under wet and dry conditions. The samples treated with copper sulphate showed colour difference but at the same time showed better fastness results. The samples treated with resin (no formaldehyde) did not alter the colour significantly still better the fastness properties. From the results, it could be stated that the resin could be an alternative for heavy metallic mordents
机译:对天然染料代替合成染料的需求不断增加,原因是前者的无毒或低毒性。合成染料与癌症等疾病有关,并且在环境中释放时需要更长的时间才能降解,并且中间体的毒性仍然更高。 Annatto(Bixa Orellana L.)是一种类胡萝卜素,是食品工业中最重要的天然染料之一。以染料的形式,它占世界天然染料产量的近70%,在巴西占90%。在目前的工作中,使用了含有近2.1%Bixin的peruana paulista物种的annatto种子。用乙醇萃取染料的过程显示出4%的粉末状染料,粒径为28mm。提取过程没有改变染料的化学组成,这通过吸收的电子光谱得以证实。在不同的条件下进行染色,以研究总色差以及在干湿条件下的耐洗牢度和耐摩擦牢度。用硫酸铜处理的样品显示出色差,但同时显示出更好的坚牢度结果。用树脂(无甲醛)处理的样品颜色没有明显改变,牢度性能也更好。从结果可以看出,该树脂可以替代重金属载体。

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