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Synergic combination of the sol-gel method with dip coating for plasmonic devices

机译:溶胶-凝胶法与浸涂等离子设备的协同组合

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摘要

Biosensing technologies based on plasmonic nanostructures have recently attracted significant attention due to their small dimensions, low-cost and high sensitivity but are often limited in terms of affinity, selectivity and stability. Consequently, several methods have been employed to functionalize plasmonic surfaces used for detection in order to increase their stability. Herein, a plasmonic surface was modified through a controlled, silica platform, which enables the improvement of the plasmonic-based sensor functionality. The key processing parameters that allow for the fine-tuning of the silica layer thickness on the plasmonic structure were studied. Control of the silica coating thickness was achieved through a combined approach involving sol-gel and dip-coating techniques. The silica films were characterized using spectroscopic ellipsometry, contact angle measurements, atomic force microscopy and dispersive spectroscopy. The effect of the use of silica layers on the optical properties of the plasmonic structures was evaluated. The obtained results show that the silica coating enables surface protection of the plasmonic structures, preserving their stability for an extended time and inducing a suitable reduction of the regeneration time of the chip.
机译:基于等离激元纳米结构的生物传感技术由于其尺寸小,成本低和灵敏度高而受到了广泛的关注,但在亲和力,选择性和稳定性方面常常受到限制。因此,已经采用了几种方法来使用于检测的等离子体表面功能化,以增加其稳定性。在此,通过受控的二氧化硅平台对等离子体表面进行了改性,从而可以改善基于等离子体的传感器功能。研究了允许在等离激元结构上微调二氧化硅层厚度的关键工艺参数。通过包括溶胶-凝胶和浸涂技术的组合方法来控制二氧化硅涂层的厚度。使用椭圆偏振光谱法,接触角测量,原子力显微镜和色散光谱对二氧化硅膜进行表征。评估了使用二氧化硅层对等离激元结构的光学性质的影响。所获得的结果表明,二氧化硅涂层能够对等离激元结构进行表面保护,在较长时间内保持其稳定性,并适当地减少了芯片的再生时间。

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