首页> 外文OA文献 >Multiscale modeling and simulation for polymer melt flows between parallel plates
【2h】

Multiscale modeling and simulation for polymer melt flows between parallel plates

机译:平行板之间聚合物熔体流动的多尺度建模和仿真

代理获取
本网站仅为用户提供外文OA文献查询和代理获取服务,本网站没有原文。下单后我们将采用程序或人工为您竭诚获取高质量的原文,但由于OA文献来源多样且变更频繁,仍可能出现获取不到、文献不完整或与标题不符等情况,如果获取不到我们将提供退款服务。请知悉。
获取外文期刊封面目录资料

摘要

The flow behaviors of polymer melt composed of short chains with ten beads between parallel plates are simulated by using a hybrid method of molecular dynamics and computational fluid dynamics. Three problems are solved: creep motion under a constant shear stress and its recovery motion after removing the stress, pressure-driven flows, and the flows in rapidly oscillating plates. In the creep/recovery problem, the delayed elastic deformation in the creep motion and evident elastic behavior in the recovery motion are demonstrated. The velocity profiles of the melt in pressure-driven flows are quite different from those of Newtonian fluid due to shear thinning. Velocity gradients of the melt become steeper near the plates and flatter at the middle between the plates as the pressure gradient increases and the temperature decreases. In the rapidly oscillating plates, the viscous boundary layer of the melt is much thinner than that of Newtonian fluid due to the shear thinning of the melt. Three different rheological regimes, i.e., the viscous fluid, viscoelastic liquid, and viscoelastic solid regimes, form over the oscillating plate according to the local Deborah numbers. The melt behaves as a viscous fluid in a region for ωτR≲1, and the crossover between the liquidlike and solidlike regime takes place around ωτα≃1 (where ω is the angular frequency of the plate and τR and τα are Rouse and α relaxation time, respectively).
机译:通过使用分子动力学和计算流体动力学的混合方法,模拟了由短链和十个小珠组成的平行链之间的聚合物熔体的流动行为。解决了三个问题:恒定剪应力下的蠕变运动,以及消除应力后的恢复运动,压力驱动的流动以及快速振荡的板中的流动。在蠕变/恢复问题中,证明了蠕变运动中的延迟弹性变形和恢复运动中明显的弹性行为。由于剪切变稀,压力驱动流中熔体的速度曲线与牛顿流体的速度曲线有很大不同。随着压力梯度的增加和温度的降低,熔体的速度梯度在板附近变陡,在板之间的中间变平。在快速振荡的板中,由于熔体的剪切稀化,熔体的粘性边界层比牛顿流体的边界层薄得多。根据当地的黛博拉数,在振动板上形成了三种不同的流变状态,即粘性流体,粘弹性液体和粘弹性固体状态。熔体在ωτR≲1的区域内表现为粘性流体,并且液状和固体状态之间的交叉发生在ωτα≃1附近(其中ω是板的角频率,τR和τα是Rouse和α弛豫时间, 分别)。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
代理获取

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号