Employing the admittance formula for double-barrier junctions [Fu and Dudley, Phys. Rev. Lett. 70, 65 (1993)], we have estimated an ac susceptance (imaginary part of admittance) of Au/1, 4-benzenedithiol/Au single-molecule junctions from their current-voltage characteristics. In the MHz regime, we find that the junction susceptance shows a very small ( ∼ 0.1 aF) capacitive component that can be entirely masked by a larger electrode capacitance. Direct ac signal transmission measurements up to 1 GHz reveal no molecular signals and confirm the smallness of the molecular capacitance in the MHz regime.
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