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Color changes in wood during heating: kinetic analysis by applying a time-temperature superposition method

机译:加热过程中木材的颜色变化:采用时间-温度叠加法进行动力学分析

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摘要

This paper deals with the kinetics of the color properties of hinoki (Chamaecyparis obtusa Endl.) wood. Specimens cut from the wood were heated at 90-180°C as accelerated aging treatment. The specimens completely dried and heated in the presence of oxygen allowed us to evaluate the effects of thermal oxidation on wood color change. Color properties measured by a spectrophotometer showed similar behavior irrespective of the treatment temperature with each time scale. Kinetic analysis using the time-temperature superposition principle, which uses the whole data set, was successfully applied to the color changes. The calculated values of the apparent activation energy in terms of L*, a*, b*, and ΔE*ab were 117, 95, 114,  and 113 kJ/mol, respectively, which are similar to the values of the literature obtained for other properties such as the physical and mechanical properties of wood.
机译:本文研究了扁柏(Chamaecyparis obtusa Endl。)木材颜色特性的动力学。从木材切下的样品在90-180°C加热,以加速老化处理。标本在氧气存在下完全干燥和加热,使我们能够评估热氧化对木材颜色变化的影响。通过分光光度计测量的颜色特性在每个时间范围内均显示出相似的行为,而与处理温度无关。使用时间-温度叠加原理进行动力学分析,该原理使用了整个数据集,已成功应用于颜色变化。以L *,a *,b *和ΔE* ab表示的表观活化能的计算值分别为117、95、114,和113 kJ / mol,与为其他性能,例如木材的物理和机械性能。

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