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A novel abbreviation standard for organobromine, organochlorine and organophosphorus flame retardants and some characteristics of the chemicals

机译:一种新的有机溴,有机氯和有机磷阻燃剂的缩写标准以及该化学品的某些特性

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摘要

Ever since the interest in organic environmental contaminants first emerged 50 years ago, there has been a need to present discussion of such chemicals and their transformation products using simple abbreviations so as to avoid the repetitive use of long chemical names. As the number of chemicals of concern has increased, the number of abbreviations has also increased dramatically, sometimes resulting in the use of different abbreviations for the same chemical. In this article, we propose abbreviations for flame retardants (FRs) substituted with bromine or chlorine atoms or including a functional group containing phosphorus, i.e. BFRs, CFRs and PFRs, respectively. Due to the large number of halogenated and organophosphorus FRs, it has become increasingly important to develop a strategy for abbreviating the chemical names of FRs. In this paper, a two step procedure is proposed for deriving practical abbreviations (PRABs) for the chemicals discussed. In the first step, structural abbreviations (STABs) are developed using specific STAB criteria based on the FR structure. However, since several of the derived STABs are complicated and long, we propose instead the use of PRABs. These are, commonly, an extract of the most essential part of the STAB, while also considering abbreviations previously used in the literature. We indicate how these can be used to develop an abbreviation that can be generally accepted by scientists and other professionals involved in FR related work. Tables with PRABs and STABs for BFRs, CFRs and PFRs are presented, including CAS (Chemical Abstract Service) numbers, notes of abbreviations that have been used previously, CA (Chemical Abstract) name, common names and trade names, as well as some fundamental physico-chemical constants.
机译:自从50年前首次出现对有机环境污染物的兴趣以来,就需要使用简单的缩写词来介绍此类化学物质及其转化产物,以避免重复使用长化学名称。随着关注的化学药品数量的增加,缩写的数量也急剧增加,有时会导致同一化学药品使用不同的缩写。在本文中,我们提出了用溴或氯原子取代或包括含磷官能团的阻燃剂(FR)的缩写,分别是BFR,CFR和PFR。由于大量的卤代和有机磷FR,开发一种缩写FRs化学名称的策略变得越来越重要。在本文中,提出了一个两步过程来导出所讨论化学物质的实际缩写(PRAB)。第一步,使用基于FR结构的特定STAB标准开发结构缩写(STAB)。但是,由于派生的几个STAB既复杂又长,我们建议改用PRAB。这些通常是STAB最重要部分的摘录,同时还考虑了以前在文献中使用的缩写。我们指出了如何使用它们来开发缩写,这些缩写通常会被科学家和参与FR相关工作的其他专业人员普遍接受。列出了含BFR,CFR和PFR的PRAB和STAB的表格,包括CAS(化学文摘社)编号,以前使用的缩写注释,CA(化学文摘)名称,通用名称和商品名称,以及一些基本信息理化常数。

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