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Abnormal magnetic behaviour of powder metallurgy austenitic stainless steels sintered in nitrogen

机译:氮烧结粉末冶金奥氏体不锈钢的异常磁行为

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摘要

The magnetic response of AISI 304L and AISI 316L obtained through powder metallurgy and sintered in nitrogen were studied. AISI 304L sintered in nitrogen showed a ferromagnetic behaviour in as-sintered state while AISI 316L was paramagnetic. After solution annealing both were paramagnetic. Magnetic behaviour was analysed by using a vibrating sample magnetometer, a magnetic ferritscope and magnetic etching. A microstructural characterization was performed by means of optical metallography, X-ray diffraction, scanning electron microscopy (SEM) and energy dispersive analysis of X-rays (EDS). Some samples when needed were submitted to aged heat treatments at 675 and 875 °C for 90 min, 4, 6, 8 or 48 h. The main microstructural feature found was the presence of a lamellar constituent formed by nitride precipitates and an interlamellar matrix of austenite and/or ferrite. The abnormal magnetic response was explained based on this.
机译:研究了粉末冶金法在氮气中烧结得到的AISI 304L和AISI 316L的磁响应。在氮气中烧结的AISI 304L在烧结状态下显示出铁磁行为,而AISI 316L是顺磁性的。固溶退火后,两者均为顺磁性。通过使用振动样品磁力计,磁铁素体计和磁蚀刻来分析磁行为。通过光学金相,X射线衍射,扫描电子显微镜(SEM)和X射线能量色散分析(EDS)进行了微观结构表征。必要时,将一些样品在675和875°C下进行90分钟,4、6、8或48小时的时效热处理。发现的主要微观结构特征是存在由氮化物沉淀和奥氏体和/或铁素体的层间基质形成的层状成分。据此解释了异常的磁响应。

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