PMMA-sepiolite nanocomposites as new promising materials for the production of nanocellular polymers

摘要

In this work, a new system based on poly(methyl methacrylate) (PMMA) sepiolite nanocompositesthat allow producing nanocellular polymers by using the gas dissolution foaming techniqueis described. Nanocomposites with different nanoparticle types and contents have been producedby extrusion. From these blends, cellular materials have been fabricated using the so-called gasdissolution foaming method. An extensive study of the effect of the processing parameters (saturationpressure and foaming temperature) on the cellular materials produced has been performed.Results showed that among the three sepiolites used, only those modified with a quaternaryammonium salt are suitable for being used as nucleating agents in PMMA. With thesenanoparticles bimodal cellular polymers, with micro and nanometric cells, have been produced.Cell sizes in the range of 300–500 nm and cell densities of the order of 1013–1014 nuclei/cm3have been obtained in the nanocellular region. A foaming temperature of 80 °C and a wide rangeof saturation pressures (between 10 and 30 MPa) and low particle contents (between 0.5 and1.5 wt%) allow obtaining these materials. Furthermore, it has been found that cell size in thenanometric population can be controlled by means of the particles content; a reduction in the cell size is obtained when the particles content increases. Finally, results indicate that an increase in the foaming temperature leads to cellular nanocomposites with lower relative densities (below 0.21) and larger cell sizes (above 450 nm).