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State equation for shape-memory alloys. Aplication to Cu-Zn-Al

机译:形状记忆合金的状态方程。在铜锌铝中的应用

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摘要

We deal with the hysteretic behavior of partial cycles in the two¿phase region associated with the martensitic transformation of shape¿memory alloys. We consider the problem from a thermodynamic point of view and adopt a local equilibrium formalism, based on the idea of thermoelastic balance, from which a formal writing follows a state equation for the material in terms of its temperature T, external applied stress ¿, and transformed volume fraction x. To describe the striking memory properties exhibited by partial transformation cycles, state variables (x,¿,T) corresponding to the current state of the system have to be supplemented with variables (x,¿,T) corresponding to points where the transformation control parameter (¿¿ and/or T) had reached a maximum or a minimum in the previous thermodynamic history of the system. We restrict our study to simple partial cycles resulting from a single maximum or minimum of the control parameter. Several common features displayed by such partial cycles and repeatedly observed in experiments lead to a set of analytic restrictions, listed explicitly in the paper, to be verified by the dissipative term of the state equation, responsible for hysteresis. Finally, using calorimetric data of thermally induced partial cycles through the martensitic transformation in a Cu¿Zn¿Al alloy, we have fitted a given functional form of the dissipative term consistent with the analytic restrictions mentioned above.
机译:我们处理了与形状记忆合金的马氏体相变有关的两相区域中部分循环的滞后行为。我们从热力学角度考虑问题,并基于热弹平衡的思想采用局部平衡形式主义,从形式主义的角度出发,遵循材料的温度T,外部施加应力¿和变换后的体积分数x。为了描述部分转换周期表现出的惊人的存储特性,必须将与系统当前状态相对应的状态变量(x,¿,T)补充与转换控制参数所在的点相对应的变量(x,¿,T) (?和/或T)在系统的先前热力学历史中已达到最大值或最小值。我们将研究限于由单个最大或最小控制参数产生的简单局部循环。由这种局部循环显示并在实验中反复观察到的几个共同特征导致了一组分析限制,这些限制已在论文中明确列出,并由引起滞后的状态方程的耗散项加以验证。最后,使用在Cu?Zn?Al合金中通过马氏体相变的热诱导局部循环的量热数据,我们拟合了给定函数形式的耗散项,与上述分析限制相一致。

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