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Martensitic transitions and the nature of ferromagnetism in the austenitic and martensitic states of Ni-Mn-Sn alloys

机译:Ni-Mn-Sn合金在奥氏体和马氏体状态下的马氏体转变和铁磁性的性质

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摘要

Structural and magnetic transformations in the Heusler-based system Ni0.50Mn0.50¿xSnx are studied by x-ray diffraction, optical microscopy, differential scanning calorimetry, and magnetization. The structural transformations are of austenitic-martensitic character. The austenite state has an L21 structure, whereas the structures of the martensite can be 10M , 14M , or L10 depending on the Sn composition. For samples that undergo martensitic transformations below and around room temperature, it is observed that the magnetic exchange in both parent and product phases is ferromagnetic, but the ferromagnetic exchange, characteristic of each phase, is found to be of different strength. This gives rise to different Curie temperatures for the austenitic and martensitic states.
机译:通过X射线衍射,光学显微镜,差示扫描量热法和磁化研究了基于Heusler的Ni0.50Mn0.50¿xSnx系统的结构和磁转变。结构转变具有奥氏体-马氏体特征。奥氏体状态具有L21结构,而根据Sn组成,马氏体的结构可以为10M,14M或L10。对于在室温以下及室温附近发生马氏体转变的样品,观察到母相和产物相中的磁交换都是铁磁性的,但是发现每个相的特征的铁磁交换具有不同的强度。这导致了奥氏体和马氏体状态的居里温度不同。

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