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Organic-rich shales from internal Betic basins (SE Spain): potential source rocks analogs for the pre-Messinian Salt play in the western Mediterranean

机译:来自贝特盆地内部的富含有机物的页岩(西班牙东南部):西地中海前迈西尼期盐矿的潜在烃源岩类似物

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摘要

under an overall NNW-SSE compressional regime related to the African-European tectonic plates collision. Located in the Betic Cordillera, they can be considered as marginal Mediterranean basins that became gradually isolated during the Tortonian and Early Messinian due to tectonic uplift. Different evaporitic units accumulated in these basins during isolation and, in several cases, evaporitic conditions were associated to episodes of important organic matter accumulation. Results obtained from Late Tortonian to Early Messinian shales collected from boreholes, mines and outcrops in the internal Betic basins of Las Minas de Hellín, Cenajo and Socovos are presented. The organic matter was studied under fluorescence and scanning electron microscopy (SEM), and the main geochemical characteristics defined. They show a relation between organic-rich intervals with high potential of hydrocarbon generation, native sulfur, bio-induced dolomite and evaporitic deposits. These organicrich shales can be found before, during and after the evaporitic episodes. Results from the present study are compared with those previously obtained in the pre-evaporitic deposits of the Lorca Basin that showed high oil generation potential, a restricted-marine origin of the organic matter and a low degree of maturity. The occurrence of such potential source rocks in several basins points to a broad regional distribution. At a larger scale, in the Mediterranean Basin, organic-rich sediments were deposited before and during the Messinian Salinity Crisis. The studied examples could represent analogs for potential source rocks of the pre-Messinian salt play in the Western Mediterranean.
机译:在与非欧洲构造板块碰撞有关的整个NNW-SSE压缩体制下。它们位于比蒂科迪勒拉(Betic Cordillera),可以认为是边缘地中海盆地,由于构造隆升而在Tortonian和Messinian早期逐渐变得孤立。在隔离过程中,这些盆地中积累了不同的蒸发单元,在某些情况下,蒸发条件与重要的有机物积累有关。给出了从拉斯米纳斯·德·海林,塞纳霍和索科沃斯内部Betic盆地的钻孔,矿山和露头收集的从晚Tortonian至Messinian页岩获得的结果。在荧光和扫描电子显微镜(SEM)下研究了有机物,并定义了主要地球化学特征。他们显示出富含有机质的层段与高潜力的烃生成,天然硫,生物诱发的白云石和蒸发沉积之间的关系。这些富含有机质的页岩可以在蒸发事件发生之前,之中和之后发现。将本研究的结果与先前在洛尔卡盆地的蒸发前沉积物中获得的结果进行了比较,这些结果显示出较高的生油潜力,受限制的海洋有机物起源和较低的成熟度。在几个盆地中这类潜在烃源岩的出现表明了广泛的区域分布。在更大范围内,在地中海盆地,在墨西尼盐度危机之前和期间沉积了富含有机物的沉积物。所研究的例子可能代表了西地中海之前的麦西尼西亚盐矿的潜在烃源岩的类似物。

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