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Microfluidic solvent extraction of copper from malachite-chalcopyrite mineral leach solution

机译:孔雀石-黄铜矿矿物浸出液中铜的微流控溶剂萃取

摘要

Microfluidics is concerned with the characteristics and manipulation of fluid flows along mili- and micro-sized channels at very low Reynolds numbers intended for specific applications. It affords improvements based on several factors such as enhanced surface area-to-volume ratio and faster diffusion which facilitate efficient extractions and phase separations. In this study, microfluidic solvent extraction (μSX) was investigated as an alternative to conventional bulk solvent extraction of copper from a mineral leach solution. While bulk extraction typically requires a two-step mixer-settler stage, μSX precludes the need of a settler. A copper solution was produced by using sulfuric acid as leachant of a composite malachite–chalcopyrite ore. A microfluidic Y-Y channel placed on the format of a microscopy polymethylmethacrylate (PMMA) slide was used for the μSX process. LIX84 (10% v/v) dissolved in Shellsol was used as the extractant. In a typical μSX application, two streams (one is the copper leach solution and the other is the extractant) are in direct parallel contact along the microsized channel. There was no observable blockage along the microfluidic channel and copper extraction was accomplished under continuous phase flow.
机译:微流体技术关注用于特定应用的极低雷诺数下流体沿着微通道和微通道的特性和操纵。它基于多种因素提供了改进,例如增加的表面积/体积比和更快的扩散,这有助于有效的萃取和相分离。在这项研究中,对微流溶剂萃取(μSX)进行了研究,以替代从矿物浸出溶液中萃取铜的常规本体溶剂。批量提取通常需要两步混合沉降器阶段,而μSX则不需要沉降器。通过使用硫酸作为孔雀石-黄铜矿复合矿石的浸出剂生产铜溶液。放置在显微聚甲基丙烯酸甲酯(PMMA)玻片上的微流控Y-Y通道用于μSX过程。溶解在Shellsol中的LIX84(10%v / v)用作提取剂。在典型的μSX应用中,两个流(一个是铜浸出溶液,另一个是萃取剂)沿微通道直接平行接触。沿微流体通道没有可观察到的堵塞,并且在连续相流下完成了铜的提取。

著录项

  • 作者

    Yin C-Y; Nikoloski A.; Wang M-W;

  • 作者单位
  • 年度 2012
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  • 原文格式 PDF
  • 正文语种 {"code":"en","name":"English","id":9}
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