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Study of various methods for the removal of arsenic contamination in groundwater

机译:去除地下水中砷污染的各种方法的研究

摘要

High concentrations of arsenic in groundwater have caused great health problems all across the world. In the present field of study, different methodologies of arsenic removal has been studied by using some hybrid materials such as Activated Charcoal (charcoal) in addition with Ferric Chloride, Coarse Calcite along with Ferric Sulphate(hydrous) and Portland Cement. These hybrid materials were prepared by sol-gel and co-precipitation method. Sodium arsenite and sodium arsenate standard solutions were used for preparing standard solutions of arsenic of required concentration. AAnalyst200 Atomic Absorbtion Spectrometer (AAS) was used for measuring the residual concentration of arsenic after the remotion techniques and parameters like pH, reaction temperature, period of time and concentration of the adsorbate/coagulant were varied to study their effects on the elimination of arsenic. These hybrid or conflated materials showed assuring results in removing arsenic from the prepared samples. The maximum efficiency showed by Activated Carbon (AC) was 96.22 percent at neutral pH, concentration: 8g/L and forced hydrolysis time period: 6 hours towards 0.05ppm As solution. The maximum efficiency showed by HPPC was 95.84 percent for pH equals to 5.1, concentration: 15g/L and adsorption period- 8hours on 0.2 ppm As solution. Coarse Calcite was the most efficient hybrid material which showed an efficiency of 99 percent at a concentration of 5g/L, pH: 4.0 and reaction time of 30 minutes against 5ppm As solution. For the same concentration of 0.2ppm, these hybrid materials were analysed and it was found that both HPPC and Coarse Calcite have nearly same efficiency of 93 percent while activated carbon took out only 50% of the As.
机译:地下水中高浓度的砷在全世界范围内引起了严重的健康问题。在当前的研究领域中,通过使用除混合氯化铁,粗方解石,硫酸亚铁(含水)和硅酸盐水泥之外的一些混合材料,例如活性炭(木炭),研究了除砷的不同方法。这些杂化材料通过溶胶-凝胶和共沉淀法制备。使用亚砷酸钠和砷酸钠标准溶液制备所需浓度的砷标准溶液。在去除技术和改变pH,反应温度,时间和吸附剂/凝结剂浓度等参数后,使用AAnalyst200原子吸收光谱仪(AAS)测量砷的残留浓度,以研究其对消除砷的影响。这些杂化或混合材料显示出从制备的样品中去除砷的保证结果。活性炭(AC)在中性pH,浓度:8g / L和强制水解时间:6小时(朝着0.05ppm As溶液)下显示的最大效率为96.22%。 HPPC所显示的最大效率是:pH等于5.1,浓度:15g / L和在0.2 ppm As溶液上吸附8小时的吸附时间为95.84%。粗方解石是最有效的杂化材料,在5g / L的浓度,pH:4.0时,相对于5ppm的As溶液,反应时间为30分钟,显示出99%的效率。对于相同的0.2ppm浓度,对这些杂化材料进行了分析,发现HPPC和粗方解石的效率几乎相同,为93%,而活性炭仅吸收了50%的As。

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    Gautam A;

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  • 年度 2014
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